Uranyl Coordination Compounds with Alkaline Earth Metals and Crotonate Ligands Full article
Journal |
ChemistrySelect
, E-ISSN: 2365-6549 |
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Output data | Year: 2019, Volume: 4, Number: 29, Pages: 8416-8423 Pages count : 8 DOI: 10.1002/slct.201901732 | ||||||||
Tags | crotonate; noncovalent interactions; structure elucidation; substructure; uranyl | ||||||||
Authors |
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Affiliations |
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Funding (2)
1 | Russian Science Foundation | 17-73-10117 |
2 | Ministry of Science and Higher Education of the Russian Federation | 0239-2019-0003 |
Abstract:
Crystal structures of three new uranyl compounds were solved using single crystal X-ray diffraction and studied using FTIR spectroscopy. Although the syntheses conditions were very similar differing only in the alkaline earth metal (Mg, Ca or Sr), the resulting structures are different, containing, respectively, mono-, tri- and hexanuclear metal-containing building units. This fact proves the profound crystal-chemical role of secondary metal atoms on the formation of crystal structures. Parameters of alkaline earth metal cations in the three newly synthesized compounds as well as in the earlier reported Ba-containing analog are discussed in detail using Voronoi–Dirichlet polyhedra and the method of intersecting spheres. Differences in packing of building units in the four mentioned compounds, as well as inter- and intramolecular noncovalent interactions in their structures are reported. The results of analysis are consistent with the stereoatomic model of crystal structures. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
Cite:
Savchenkov A.V.
, Pirozhkov P.A.
, Vologzhanina A.V.
, Zubavichus Y.V.
, Dorovatovskii P.V.
, Pushkin D.V.
, Serezhkina L.B.
Uranyl Coordination Compounds with Alkaline Earth Metals and Crotonate Ligands
ChemistrySelect. 2019. V.4. N29. P.8416-8423. DOI: 10.1002/slct.201901732 WOS Scopus РИНЦ
Uranyl Coordination Compounds with Alkaline Earth Metals and Crotonate Ligands
ChemistrySelect. 2019. V.4. N29. P.8416-8423. DOI: 10.1002/slct.201901732 WOS Scopus РИНЦ
Dates:
Submitted: | May 13, 2019 |
Accepted: | Jul 15, 2019 |
Published online: | Aug 1, 2019 |
Published print: | Aug 7, 2019 |
Identifiers:
Web of science | WOS:000479139200007 |
Scopus | 2-s2.0-85070203281 |
Elibrary | 41624252 |
Chemical Abstracts | 2019:1542387 |
OpenAlex | W2965541941 |
Citing:
DB | Citing |
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Elibrary | 1 |