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Fe-Containing Nickel Phosphate Molecular Sieves as Heterogeneous Catalysts for Phenol Oxidation and Hydroxylation with H2O2 Full article

Общее Language: Английский, Genre: Full article,
Status: Published, Source type: Original
Journal Applied Catalysis B: Environmental
ISSN: 0926-3373 , E-ISSN: 1873-3883
Output data Year: 2011, Volume: 107, Number: 1-2, Pages: 197-204 Pages count : 8 DOI: 10.1016/j.apcatb.2011.07.014
Tags Hydrogen peroxide, Hydroxylation, Nickel phosphate molecular sieves VSB-5, Oxidation, Phenol
Authors Timofeeva M.N. 1 , Hasan Zubair 2 , Orlov A.Yu. 1,3 , Panchenko V.N. 1 , Chesalov Yu.A. 1 , Soshnikov I.E. 1 , Jhung Sung Hwa 2
Affiliations
1 Boreskov Institute of Catalysis SB RAS, Prospekt Akad. Lavrentieva 5, 630090, Novosibirsk, Russian Federation
2 Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University, Sankyuck-Dong, Buk-Ku, Daegu 702-701, South Korea
3 Novosibirsk State University, st. Pirogova 2, 630090, Novosibirsk, Russian Federation

Funding (1)

1 Korea Sanhak Foundation

Abstract: Fe-containing nickel phosphate molecular sieves (Fe-VSB-5) were hydrothermally synthesized in weak basic conditions under microwave irradiation and characterized by SEM, XRD, N2-adsorption/desorption, DRS-UV–vis, and FT-IR spectroscopy using PhCN and CDCl3 as probe molecules. The catalytic activity of Fe-VSB-5 was tested for the phenol hydroxylation and wet phenol oxidation with H2O2. The increase in iron content in Fe-VSB-5 leds to an increase in the reaction rates. The increases in activity can be explained by the role of the Fe species, which increases the generation of radicals. The Fe-VSB-5 samples were stable against the leaching out of Fe ions. The catalytic activity of Fe-VSB-5 was compared to the catalytic activity of traditional Fe-containing materials.
Cite: Timofeeva M.N. , Hasan Z. , Orlov A.Y. , Panchenko V.N. , Chesalov Y.A. , Soshnikov I.E. , Jhung S.H.
Fe-Containing Nickel Phosphate Molecular Sieves as Heterogeneous Catalysts for Phenol Oxidation and Hydroxylation with H2O2
Applied Catalysis B: Environmental. 2011. V.107. N1-2. P.197-204. DOI: 10.1016/j.apcatb.2011.07.014 publication_identifier_short.wos_identifier_type publication_identifier_short.scopus_identifier_type publication_identifier_short.rinz_identifier_type
Dates:
Submitted: May 24, 2011
Accepted: Jul 10, 2011
Published online: Jul 20, 2011
Published print: Aug 1, 2011
Identifiers:
publication_identifier.wos_identifier_type WOS:000294883300024
publication_identifier.scopus_identifier_type 2-s2.0-80051468941
publication_identifier.rinz_identifier_type 16997290
publication_identifier.accession_number_identifier_type 2011:1023572
publication_identifier.chemical_accession_number_identifier_type 155:355335
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