Binuclear Metallochelates of 2-(N-tosylamino)benzal-2’-(hydroxymethyl)aniline: Syntheses, Structures, and Magnetic Properties Full article
Journal |
Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318 |
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Output data | Year: 2016, Volume: 42, Number: 4, Pages: 267-273 Pages count : 7 DOI: 10.1134/s1070328416030027 | ||||||||
Tags | Coordination Chemistry; Binuclear Complex; Upfield Shift; Attenuate Total Internal Reflectance; Copper Acetate Monohydrate | ||||||||
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Abstract:
Binuclear complexes of Co(II), Сu(II), and Pd(II) with 2-(N-tosylamino)benzal-2’-(hydroxymethyl)aniline are synthesized. The compositions and structures of the ligand and complexes are determined from the data of elemental analysis, IR spectroscopy, 1Н, 13С, and 15N NMR spectroscopy, X-ray absorption spectroscopy, and magnetochemical measurements in a temperature range of 294–77.4 K. All complexes are dimeric. The Cu…Cu and Cо…Cо distances equal to 3.03 and 2.99 Å, respectively, are obtained for the Cu(II) and Co(II) complexes. These complexes are characterized by the antiferromagnetic exchange interaction with 2J = –630 and –42 cm–1, respectively.
Cite:
Burlov A.S.
, Vlasenko V.G.
, Koshchienko Y.V.
, Levchenkov S.I.
, Pankov I.V.
, Zubavichus Y.V.
, Trigub A.L.
, Borodkin G.S.
, Mazepina T.A.
, Garnovskii D.A.
, Uraev A.I.
Binuclear Metallochelates of 2-(N-tosylamino)benzal-2’-(hydroxymethyl)aniline: Syntheses, Structures, and Magnetic Properties
Russian Journal of Coordination Chemistry. 2016. V.42. N4. P.267-273. DOI: 10.1134/s1070328416030027 WOS Scopus РИНЦ
Binuclear Metallochelates of 2-(N-tosylamino)benzal-2’-(hydroxymethyl)aniline: Syntheses, Structures, and Magnetic Properties
Russian Journal of Coordination Chemistry. 2016. V.42. N4. P.267-273. DOI: 10.1134/s1070328416030027 WOS Scopus РИНЦ
Original:
Бурлов А.С.
, Власенко В.Г.
, Кощиенко Ю.В.
, Левченков С.И.
, Панков И.В.
, Зубавичус Я.В.
, Тригуб А.Л.
, Бородкин Г.С.
, Мазепина Т.А.
, Гарновский Д.А.
, Ураев А.И.
Синтез, строение, магнитные свойства биядерных металлохелатов 2-(N-тозиламино)бензаль-2'- (гидроксиметил)анилина
Координационная химия. 2016. Т.42. №4. С.237-244. DOI: 10.7868/S0132344X16030026 РИНЦ
Синтез, строение, магнитные свойства биядерных металлохелатов 2-(N-тозиламино)бензаль-2'- (гидроксиметил)анилина
Координационная химия. 2016. Т.42. №4. С.237-244. DOI: 10.7868/S0132344X16030026 РИНЦ
Dates:
Submitted: | Jul 22, 2015 |
Published print: | Apr 1, 2016 |
Published online: | May 7, 2016 |
Identifiers:
Web of science | WOS:000376025100004 |
Scopus | 2-s2.0-84966699816 |
Elibrary | 27159645 |
Chemical Abstracts | 2016:742333 |
Chemical Abstracts (print) | 167:338098 |
OpenAlex | W2346909879 |