Conversion of n-Butylamine in the Course of Synthesis from Carbon Monoxide and Hydrogen ArticleGenre_short.SHORT_COMMUNICATION
Journal |
Bulletin of the Academy of Sciences of the USSR. Division of Chemical Sciences (1951 - 1992)
ISSN: 0568-5230 |
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Output data | Year: 1959, Volume: 8, Number: 7, Pages: 1299-1300 Pages count : 2 DOI: 10.1007/bf00920423 | ||
Tags | Hydrogen; Iron; Carbon Monoxide; Direct Synthesis; Aliphatic Amine | ||
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Abstract:
The direct synthesis of aliphatic amines from CO, H 2 and NH s in the presence of fused iron catalysts was accomplished previously [1,2]. The amines thus obtained consisted predominantly of monoalkylamines together with a small amount of secondary and tertiary amines [2]. It was established that the formation of di- and trialkylamines was promoted by conditions favoring a reaction between primary amines formed during the synthesis and oxygen-containing products from the hydrogenation of carbon dioxide (alcohols, aldehydes etc.). This led to the hypothesis that secondary and tertiary amines could be obtained by the introduction of primary amines into the zone of synthesis from CO and H 2. The purpose of the present work was to test this hypothesis
Cite:
Kagan Y.B.
, Bashkirov A.N.
, Kliger G.A.
, Ermakov Y.I.
Conversion of n-Butylamine in the Course of Synthesis from Carbon Monoxide and Hydrogen
Bulletin of the Academy of Sciences of the USSR. Division of Chemical Sciences (1951 - 1992). 1959. V.8. N7. P.1299-1300. DOI: 10.1007/bf00920423 Scopus РИНЦ
Conversion of n-Butylamine in the Course of Synthesis from Carbon Monoxide and Hydrogen
Bulletin of the Academy of Sciences of the USSR. Division of Chemical Sciences (1951 - 1992). 1959. V.8. N7. P.1299-1300. DOI: 10.1007/bf00920423 Scopus РИНЦ
Original:
Каган Ю.Б.
, Башкиров А.Н.
, Клигер Г.А.
, Ермаков Ю.И.
Превращения н.бутиламина в условиях синтеза из окиси углерода и водорода
Известия Академии наук СССР. Серия химическая (с 1991 г. Известия Академии наук. Серия химическая). 1959. №7. С.1345-1346. РИНЦ
Превращения н.бутиламина в условиях синтеза из окиси углерода и водорода
Известия Академии наук СССР. Серия химическая (с 1991 г. Известия Академии наук. Серия химическая). 1959. №7. С.1345-1346. РИНЦ
Dates:
Submitted: | Jan 19, 1959 |
Published print: | Jul 1, 1959 |
Identifiers:
Scopus | 2-s2.0-34250594101 |
Elibrary | 30880047 |
OpenAlex | W2051946146 |
Citing:
Пока нет цитирований