Study on the Interaction of Surface Alkyl and Hydride Compounds of Ti, Zr, and Hf with Carbon monoxide Full article
Conference |
5th International Symposium on Relations Between Homogeneous and Heterogeneous Catalysis 15-19 Jul 1986 , Новосибирск |
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Source | Homogeneous and Heterogeneous Catalysis: Proceedings of the Fifth International Symposium on Relations Between Homogeneous and Heterogeneous Catalysis, USSR Compilation, CRC Press. 1986. 1170 c. ISBN 9789067640732. |
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Output data | Year: 1986, Pages: 647-660 Pages count : 14 | ||
Tags | carbon monoxide interaction alkyl hydride compound; transition metal alkylhydride surface reaction; alkyl transition metal interaction carbon monoxide; hydride transition metal interaction carbon monoxide; adsorption carbon monoxide surface alkyl hydride; insertion carbon monoxide surface alkyl hydride | ||
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Abstract:
The interaction of CO with surface compounds with the composition (Si-O) MR (M = Ti, Zr, Hf; R = CH2Ph,H; n = 1-3) was studied by using IR spectroscopy. The interaction of CO with surface benzyl and hydride compounds of Ti, Zr, and Hf follows a 2-stage mechanism. At 170-250 K a reversible adsorption of CO on a transition metal ion was observed With CO adsorption at >293 K, CO inserted into the metal-H and metal-alkyl bonds to give surface formyl and acyl compounds.
Cite:
Nesterov G.A.
, Zakharov V.A.
, Vasnetsov S.A.
, Paukshtis E.A.
Study on the Interaction of Surface Alkyl and Hydride Compounds of Ti, Zr, and Hf with Carbon monoxide
In compilation Homogeneous and Heterogeneous Catalysis: Proceedings of the Fifth International Symposium on Relations Between Homogeneous and Heterogeneous Catalysis, USSR. – CRC Press., 1986. – C.647-660. – ISBN 9789067640732.
Study on the Interaction of Surface Alkyl and Hydride Compounds of Ti, Zr, and Hf with Carbon monoxide
In compilation Homogeneous and Heterogeneous Catalysis: Proceedings of the Fifth International Symposium on Relations Between Homogeneous and Heterogeneous Catalysis, USSR. – CRC Press., 1986. – C.647-660. – ISBN 9789067640732.
Identifiers:
Chemical Abstracts | 1987:605980 |
Chemical Abstracts (print) | 107:205980 |
Citing:
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