Crystal Structure of Tris- (2,3,5,6-Tetrafluorobenzoato)Scandium [Sc(C6F4HCO2)3] Full article
Journal |
Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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Output data | Year: 2018, Volume: 59, Number: 2, Pages: 494-496 Pages count : 3 DOI: 10.1134/s0022476618020348 | ||||||||
Tags | scandium complexes, coordination polymer, tetrafluoroterephthalic acid, tetrafluorobenzoic acid, crystal structure | ||||||||
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Abstract:
The heating of a mixture of as-precipitated scandium hydroxide and tetrafluoroterephthalic acid in methanol is accompanied by acid decarboxylation and the formation of a tris-(2,3,5,6- tetrafluorobenzoato)scandium complex compound. According to the data of the single crystal X-ray diffraction analysis, the compound has a chain structure due to the carboxylate anion functioning as a μ2-bridging ligand. The polymer chains are linked together by π–π interactions between the phenyl rings.
Cite:
Cheplakova A.M.
, Fedoseev I.S.
, Dorovatovskii P.V.
, Lazarenko V.A.
, Zubavichus Y.V.
, Khrustalev V.N.
, Fedin V.P.
Crystal Structure of Tris- (2,3,5,6-Tetrafluorobenzoato)Scandium [Sc(C6F4HCO2)3]
Journal of Structural Chemistry. 2018. V.59. N2. P.494-496. DOI: 10.1134/s0022476618020348 WOS Scopus РИНЦ
Crystal Structure of Tris- (2,3,5,6-Tetrafluorobenzoato)Scandium [Sc(C6F4HCO2)3]
Journal of Structural Chemistry. 2018. V.59. N2. P.494-496. DOI: 10.1134/s0022476618020348 WOS Scopus РИНЦ
Original:
Чеплакова А.М.
, Федосеев И.С.
, Дороватовский П.В.
, Лазаренко В.А.
, Зубавичус Я.В.
, Хрусталёв В.Н.
, Федин В.П.
Кристаллическая структура трис-(2,3,5,6-тетрафторбензоатo)скандия [Sc(C6F4HCO2)3]
Журнал структурной химии. 2018. Т.59. №2. С.505-508. DOI: 10.26902/JSC20180234 РИНЦ
Кристаллическая структура трис-(2,3,5,6-тетрафторбензоатo)скандия [Sc(C6F4HCO2)3]
Журнал структурной химии. 2018. Т.59. №2. С.505-508. DOI: 10.26902/JSC20180234 РИНЦ
Dates:
Submitted: | Apr 7, 2017 |
Published print: | Mar 1, 2018 |
Published online: | Jul 3, 2018 |
Identifiers:
Web of science | WOS:000434477700034 |
Scopus | 2-s2.0-85048144014 |
Elibrary | 35775023 |
Chemical Abstracts | 2018:1096768 |
OpenAlex | W2794752317 |