Polyfunctional Branched Metallosiloxane Oligomers and Composites Based on Them
Full article
| Common |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Original
|
| Journal |
Journal of Organometallic Chemistry
ISSN: 0022-328X
|
| Output data |
Year: 2018,
Volume: 868,
Pages: 112-121
Pages count
: 10
DOI:
10.1016/j.jorganchem.2018.04.011
|
| Tags |
Alkoxysilanes; Rebrov salts; Metalloalkoxysiloxanes; Polycondensation; Silicate compositions;
Sol-gel method |
| Authors |
Tebeneva N.A.
1
,
Meshkov I.B.
1
,
Тarasenkov А.N.
1
,
Polshchikova N.V.
2
,
Кalinina A.A.
1
,
Buzin M.I.
2
,
Serenko О.А.
2
,
Zubavichus Y.V.
3
,
Katsoulis D.E.
4
,
Мuzafarov А.М.
1,2
|
| Affiliations |
| 1 |
N.S. Enikolopov Institute of Synthetic Polymeric Materials of Russian Academy of Sciences (ISPM RAS)
|
| 2 |
A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences (INEOS RAS)
|
| 3 |
National Research Center «Kurchatov Institute»
|
| 4 |
Dow Corning Corporation
|
|
New ethoxy-functional metallosiloxanes with a high activity in alkoxysilane polycondensation reactions have been synthesized with the use of Rebrov salts. A possibility of using the obtained methyldiethoxysiloxy derivatives of metallosiloxanes as binders for the preparation of homogeneous polydimethylsiloxane-containing compositions by realizing the concept of “liquid filling” has been demonstrated. The properties of the resulting compositions have been studied.