Electron Paramagnetic Resonance of Copper bis-(2-Hydroxy-Substituted Camphorates) and Their Adducts with Donor Bases Full article
Journal |
Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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Output data | Year: 1975, Volume: 16, Number: 5, Pages: 719-723 Pages count : 5 DOI: 10.1007/BF00748076 | ||
Tags | Copper; Physical Chemistry; Inorganic Chemistry; Adduct; Electron Paramagnetic Resonance | ||
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Abstract:
The reactions of Cu (II) bis-(2-hydroxy-substituted camphorates), (2-hydroxymethylenecamphorate
Cu(mcam) 2, 2-hydroxybenzylidenecamphorate Cu(bcam) 2, and 2-hydroxytrifluoroethylidenecamphorate
Cu(tfcam)~, as well as the complex of 2-hydroxymethylenementhonate Cu(omm) 2 with certain
electron-donor bases were studied by the EPR method. Depending on the donor-acceptor properties
of the chelate and donor, a structure is obtained with an axial or plaNar coordination of one or two
molecules of the adduct base. Equilibrium constants were determined for the reaction of
CuL z +Py ~ CuL~Py in toluene at 20"C. The most stable adducts with pyridine are given by the Cu(tfcam) 2
complex (K = 1000 liter/mole), while the stabilities of the pyridine adducts with each of the three
remaining complexes are approximately the same (K = 80 liter/mole). Steric factors influence the
stabilization of the structure of the Cu (II) camphorate adducts.
Cite:
Geraseva N.A.
, Shklyaev A.A.
, Anufrienko V.F.
Electron Paramagnetic Resonance of Copper bis-(2-Hydroxy-Substituted Camphorates) and Their Adducts with Donor Bases
Journal of Structural Chemistry. 1975. V.16. N5. P.719-723. DOI: 10.1007/BF00748076 WOS Scopus РИНЦ
Electron Paramagnetic Resonance of Copper bis-(2-Hydroxy-Substituted Camphorates) and Their Adducts with Donor Bases
Journal of Structural Chemistry. 1975. V.16. N5. P.719-723. DOI: 10.1007/BF00748076 WOS Scopus РИНЦ
Original:
Герасева Н.А.
, Шкляев А.А.
, Ануфриенко В.Ф.
ЭПР бис-(2-окси-замещенных камфоранов) меди и их аддуктов с донорными основаниями
Журнал структурной химии. 1975. Т.16. №5. С.774-779. РИНЦ
ЭПР бис-(2-окси-замещенных камфоранов) меди и их аддуктов с донорными основаниями
Журнал структурной химии. 1975. Т.16. №5. С.774-779. РИНЦ
Dates:
Submitted: | Jan 13, 1975 |
Published print: | Sep 1, 1976 |
Identifiers:
Web of science | WOS:A1975BZ05700009 |
Scopus | 2-s2.0-34250399121 |
Elibrary | 29831353 |
OpenAlex | W2333249012 |
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