Study of Copper bis-Salicylaldehydate Complex (Cu(Salald)2) and Its Adducts with Different Bases by EPR and IR Spectroscopic Methods
Full article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Translated
|
| Journal |
Journal of Structural Chemistry
ISSN: 0022-4766
, E-ISSN: 1573-8779
|
| Output data |
Year: 1983,
Volume: 24,
Number: 2,
Pages: 185-188
Pages count
: 4
DOI:
10.1007/BF00747376
|
| Authors |
Talzi E.P.
1
,
Nekipelov V.M.
1
,
Zamaraev K.I.
1
|
| Affiliations |
| 1 |
Boreskov Institute of Catalysis SB RAS
|
|
By using EPR and IR spectroscopy methods it was found that Cu(Salald)2 exists in slightly polar solvents in the form of two isomers, which are possibly cis--trans isomers with a close to planar structure. The adduct formation of Cu(Salald) 2 with weak bases practically does not influence its isomeric composition, while the addition of strong bases leads to a preferential stabilization of one of the isomers, probably the trans-isomer.