NMR and Magnetic-Relaxation Study of the Structure of the Products of the Reaction of Aluminum tris(Acetylacetonate) with Aluminum Chloride in a Chloroform Solution
Journal of Structural Chemistry
, E-ISSN: 1573-8779
Boreskov Institute of Catalysis SB RAS
It has been shown with the aid of NMR that the reaction of aluminum acetylacetonate [Al(acac) 3] with AICI 3 and CHCI 3 results in the formation of Al(acac)2Cl and Al(acac)Cl=. The dimensions of the complexes formed have been determined, and it has been concluded on their basis that the complexes are monomeric. The structures of the compounds formed have been proposed. The data obtained attest to the fact that Al(acac)Cl 2 has a tetrahedral configuration of ligands.