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Cocatalytic Effect of Palladium and Zinc in the Condensation of Alcohol Carbon Backbones into Hydrocarbons Full article

Общее Language: Английский, Genre: Full article,
Status: Published, Source type: Translated
Journal Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Output data Year: 2011, Volume: 52, Number: 2, Pages: 258-272 Pages count : 5 DOI: 10.1134/S0023158411020030
Authors Chistyakov A.V. 1 , Tsodikov M.V. 1 , Murzin V.Yu. 1 , Yandieva F.A. 1 , Zubavichus Yu.V. 2 , Kozitsyna N.Y. 3 , Gekhman A.E. 3 , Kriventsov V.V. 4 , Moiseev I.I. 1
Affiliations
1 A.V. Topchiev Institute of Petrochemical Synthesis RAS
2 National Research Centre "Kurchatov Institute"
3 Kurnakov Institute of General and Inorganic Chemistry RAS
4 Boreskov Institute of Catalysis SB RAS

Abstract: The results of the direct conversion of ethanol and its mixture with glycerol into a C4–C10+ alkane and olefin fraction in the presence of Pd-, Zn-, and Pd-Zn-containing catalysts, which were prepared by supporting homo- and heterometallic acetate complexes onto the surface of γ-Al2O3, are reported. It was found that, in the presence of mono- and bicomponent Pd-ZnO (Pd; ZnO)/γ-Al2O3 systems, selectivity in the formation of alkanes, olefins, or their mixtures in the target fraction can be controlled as a result of the cocatalytic effect of active components that are responsible for the catalyst activity in condensation and hydrogenation reactions. The structures of the active components were studied and the genesis of the catalytic systems was characterized using XAFS, XPS, and XRD analysis. It was found that the addition of glycerol considerably increased the yield of the target hydrocarbon fraction.
Cite: Chistyakov A.V. , Tsodikov M.V. , Murzin V.Y. , Yandieva F.A. , Zubavichus Y.V. , Kozitsyna N.Y. , Gekhman A.E. , Kriventsov V.V. , Moiseev I.I.
Cocatalytic Effect of Palladium and Zinc in the Condensation of Alcohol Carbon Backbones into Hydrocarbons
Kinetics and Catalysis. 2011. V.52. N2. P.258-272. DOI: 10.1134/S0023158411020030 publication_identifier_short.wos_identifier_type publication_identifier_short.scopus_identifier_type publication_identifier_short.rinz_identifier_type
ArticleLinkType.TRANSLATED_TO_ORIGINAL: Чистяков А.В. , Цодиков М.В. , Мурзин В.Ю. , Яндиева Ф.А. , Зубавичус Я.В. , Козицына Н.Ю. , Гехман А.Е. , Кривенцов В.В. , Моисеев И.И.
Сокаталитический эффект палладия и цинка в реакции конденсации углеродного остова спиртов в углеводороды
Кинетика и катализ. 2011. Т.52. №2. С.266-281. publication_identifier_short.rinz_identifier_type
Dates:
Submitted: Jul 2, 2010
Published print: Mar 1, 2011
Published online: Apr 7, 2011
Identifiers:
publication_identifier.wos_identifier_type WOS:000289254900016
publication_identifier.scopus_identifier_type 2-s2.0-79953845617
publication_identifier.rinz_identifier_type 16991671
publication_identifier.accession_number_identifier_type 2011:438065
publication_identifier.chemical_accession_number_identifier_type 154:567160
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