Self-Sustained Oscillations in CO Oxidation Reaction on PdO/Al2O3 Catalyst
Full article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Original
|
| Journal |
Chemical Engineering Science
ISSN: 0009-2509
, E-ISSN: 1873-4405
|
| Output data |
Year: 2012,
Volume: 83,
Pages: 149-158
Pages count
: 9
DOI:
10.1016/j.ces.2012.03.020
|
| Tags |
Catalysis, CO oxidation, Experiment, Feedback mechanism, Mathematical modeling, Self-oscillations |
| Authors |
Lashina E.A.
1
,
Slavinskaya E.M.
1
,
Chumakova N.A.
1,3
,
Stonkus O.A.
1,3
,
Gulyaev R.V.
1
,
Stadnichenko A.I.
1,3
,
Chumakov G.A.
2,3
,
Boronin A.I.
1,3
,
Demidenko G.V.
2,3
|
| Affiliations |
| 1 |
Boreskov Institute of Catalysis SB RAS, pr. Akad. Lavrent’eva 5, Novosibirsk 630090, Russia
|
| 2 |
Sobolev Institute of Mathematics SB RAS, pr. Akad. Koptyuga 4, Novosibirsk 630090, Russia
|
| 3 |
Novosibirsk State University, ul. Pirogova 2, Novosibirsk 630090, Russia
|
|
Funding (1)
The paper presents the experimental study and mathematical modeling of self-sustained oscillations in the reaction of CO oxidation on PdO/Al2O3 catalysts. In experiments we observe the complicated multi-peak oscillatory behavior of CO conversion under isothermal conditions. At these, the palladium surface is composed of a mixture of the metallic and oxide phases. We develop some new mathematical models describing the interaction of reagents with the Pd and PdO surfaces and taking into account the influence of the reaction medium on the catalyst activity. The models qualitatively describe the relaxation and multi-peak oscillations of the CO conversion. The redox process of Pd–PdO transition observed in the experiment causes the relaxation oscillations, while the mixed-mode oscillations in the model are observed due to coupling between the deep oxidation of palladium and the surface modification by oxygen.