Reduction of Nitrotoluenes in Supercritical Isopropanol over Al2O3 in a Flow Reactor
Full article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Translated
|
| Journal |
Russian Journal of Physical Chemistry A
ISSN: 0036-0244
, E-ISSN: 1531-863X
|
| Output data |
Year: 2015,
Volume: 89,
Number: 2,
Pages: 202-206
Pages count
: 5
DOI:
10.1134/S0036024415020314
|
| Tags |
alkoxylation, aluminum oxide, hydride transfer, nitrotoluene, reduction, supercritical isopropanol, toluidine |
| Authors |
Sivcev V.P.
1
,
Korchagina D.V.
2
,
Volcho K.P.
2,3
,
Salakhutdinov N.F.
2,3
,
Anikeev V.I.
1
|
| Affiliations |
| 1 |
Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
|
| 2 |
Vorozhtsov Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
|
| 3 |
Novosibirsk State University, Novosibirsk, Russia
|
|
Funding (1)
|
1
|
Russian Foundation for Basic Research
|
14-08-00210
|
The reduction of o-, m-, and p-nitrotoluenes in supercritical isopropanol over Al2O3 in a flow reactor is studied. It is shown that corresponding toluidines are major reaction products. Aromatic ring alkoxylation and N-alkylation products make a considerable contribution to the composition of reaction mixtures