Structural and Catalytic Properties of Pd/Al2O3-La2O3 Catalysts
Full article
Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Original
|
Conference |
Environmental Catalysis : Symposium held at the 5th Chemical Congress of North America
11-15 Nov 1997
,
Cancún
|
Journal |
Catalysis Today
ISSN: 0920-5861
, E-ISSN: 1873-4308
|
Output data |
Year: 2000,
Volume: 55,
Number: 3,
Pages: 301-309
Pages count
: 9
DOI:
10.1016/S0920-5861(99)00241-2
|
Tags |
NH3 production, Nitrogen oxide reduction, Pd/Al2O3-La2O3 catalysts, Sol-gel preparation method |
Authors |
Fuentes S.
1
,
Bogdanchikova N.
1,2
,
Avalos-Borja M.
1
,
Boronin A.I.
3
,
Farı́as M.H.
1
,
Dı́az G.
4
,
Cortes A.G.
4
,
Barrera A.
1,2
|
Affiliations |
1 |
Centro de Ciencias de la Materia Condensada, UNAM (México), P.O. Box 439036, San Ysidro, CA 92143, USA
|
2 |
CICESE, Km. 107 Carretera Tijuana-Ensenada, Apdo. Postal 2732, Ensenada, B.C. Mexico
|
3 |
Institute of Catalysis, Novosibirsk, 630090 Russia
|
4 |
Instituto de Fısica, UNAM, México D.F., Mexico
|
|
Funding (2)
1
|
National Autonomous University of Mexico
|
930286
|
2
|
National Autonomous University of Mexico
|
25381-A
|
A new Pd/Al2O3–La2O3 catalyst has been synthesized for the reduction of NO with hydrogen. This catalyst is more active than coprecipitated Pd/Al2O3 catalysts. The revealed effect of the improvement of the catalytic activity at medium temperature and the increase of NH3 formation at high temperatures for Pd catalyst supported on alumina–lanthana prepared by the sol–gel method are ascribed to a new lanthanum-containing phase observed by X-ray powder diffraction and high resolution electron microscopy.