Synthesis of New Chiral Phosphorous- and Nitrogen-Containing Ligands From Resin Acids
Full article
| Common |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Original
|
| Journal |
Chirality
ISSN: 0899-0042
, E-ISSN: 1520-636X
|
| Output data |
Year: 2004,
Volume: 16,
Number: SUPPL.,
Pages: S40-S50
Pages count
: 1
DOI:
10.1002/chir.20045
|
| Tags |
Asymmetric catalysis, Bisphosphines, Dehydroabietic acid, Diterpenes, Levopimaric acid, Thioureas, Ureas |
| Authors |
Khlebnikova Tatiana B.
1
,
Karpyshev Nikolay N.
1
,
Tolstikova Olga V.
2
,
Tolstikov Alexander G.
1,2
|
| Affiliations |
| 1 |
Boreskov Institute of Catalysis, Siberian Branch of Russian Academy of Sciences, Novosibirsk, Russia
|
| 2 |
Institute of Technical Chemistry Ural’s Branch of Russian Academy of Sciences, Perm, Russia
|
|
Funding (3)
|
1
|
Russian Foundation for Basic Research
|
04-03-32425
|
|
2
|
Council for Grants of the President of the Russian Federation
|
НШ-2020.2003.3
|
|
3
|
Russian Foundation for Basic Research
|
04-03-32063
|
Starting from the phytogenic diterpenes, chiral phosphine, urea, and thiourea derivatives were synthesized. Using these new chiral ligands, Rh(I) and Ru(II) complexes were prepared and used as catalysts for the catalytic asymmetric hydrogenation of unsaturated carboxylic acids and asymmetric hydrogen-transfer reduction of carbonyl compounds. Although the enantiopurity of the products obtained was not high, it was demonstrated that chiral ligands derived from diterpenes could be used for asymmetric reduction.