X-ray Diffraction Structure Analysis of MCM-48 Mesoporous Silica Full article
Journal |
The Journal of Physical Chemistry B
ISSN: 1520-6106 , E-ISSN: 1520-5207 |
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Output data | Year: 2005, Volume: 109, Number: 8, Pages: 3233-3237 Pages count : 5 DOI: 10.1021/jp0482868 | ||||||
Tags | Adsorption; Calcination; Hydrothermal synthesis; Mathematical models; Mesoporous materials; Phase transitions; Surface active agents; Thermogravimetric analysis; Transmission electron microscopy; X ray diffraction analysis | ||||||
Authors |
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Affiliations |
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Funding (5)
1 | International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union | 01-2283 |
2 | Russian Foundation for Basic Research | 03-03-32127 |
3 | United States Department of Energy | |
4 | Federal Ministry of Education and Research | |
5 | Verband der Chemischen Industrie |
Abstract:
The structure of MCM-48 mesoporous silicate materials has been fully characterized from X-ray diffraction data by applying recently developed methods of mesostructure analysis and full-profile refinement. The pore wall thickness of both as-made and calcined MCM-48 was determined with high precision to be 8.0(1) Å. No regular variations of the wall thickness were detected, but its density was found to be ca. 10% higher in the low-curvature regions. The surfactant density in the pores was assessed around 0.6−0.7 g/cm3 and was found to have a distinct minimum in the pore center similar to that detected previously in MCM-41. A new extended model function of the density distribution in MCM-48 is proposed on the basis of the structural features that were revealed.
Cite:
Solovyov L.A.
, Belousov O.V.
, Dinnebier R.E.
, Shmakov A.N.
, Kirik S.D.
X-ray Diffraction Structure Analysis of MCM-48 Mesoporous Silica
The Journal of Physical Chemistry B. 2005. V.109. N8. P.3233-3237. DOI: 10.1021/jp0482868 WOS Scopus РИНЦ
X-ray Diffraction Structure Analysis of MCM-48 Mesoporous Silica
The Journal of Physical Chemistry B. 2005. V.109. N8. P.3233-3237. DOI: 10.1021/jp0482868 WOS Scopus РИНЦ
Dates:
Submitted: | Apr 20, 2004 |
Accepted: | Dec 3, 2004 |
Published online: | Feb 2, 2005 |
Published print: | Mar 1, 2005 |
Identifiers:
Web of science | WOS:000227247100022 |
Scopus | 2-s2.0-14844362910 |
Elibrary | 13487067 |
Chemical Abstracts | 2005:89135 |
Chemical Abstracts (print) | 142:320905 |
OpenAlex | W2089936061 |