Framework Characterization of Mesostructured Carbon CMK-1 by X-Ray Powder Diffraction and Electron Microscopy Full article
Journal |
The Journal of Physical Chemistry B
ISSN: 1520-6106 , E-ISSN: 1520-5207 |
||||||
---|---|---|---|---|---|---|---|
Output data | Year: 2002, Volume: 106, Number: 47, Pages: 12198-12202 Pages count : 5 DOI: 10.1021/jp0257653 | ||||||
Tags | Mesoporous materials; Textures; Transmission electron microscopy; X ray powder diffraction | ||||||
Authors |
|
||||||
Affiliations |
|
Funding (3)
1 | Russian Foundation for Basic Research | 02-03-97704 |
2 | International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union | YSF 2001/2-3 |
3 | International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union | 01-2283 |
Abstract:
The model of structure and structural transformation of the mesostructured carbon material CMK-1 was established by X-ray powder diffraction (XRD) and transmission electron microscopy (TEM) investigations. The investigations showed that the enantiomeric carbon subframeworks formed within the pores of the MCM-48 mesoporous template used for the material synthesis displaced with respect to one another without significant distortions after the dissolution of the silica wall of the template. The model proposed agrees well with TEM images observed. The XRD structural modeling of CMK-1 done using the continuous density function technique allowed perfect fit of the calculated to the experimental powder diffraction pattern and provided geometric characteristics of the material texture. The structural characteristics obtained agreed fairly well with TEM analysis and with previously reported adsorption data.
Cite:
Solovyov L.A.
, Zaikovskii V.I.
, Shmakov A.N.
, Belousov O.V.
, Ryoo R.
Framework Characterization of Mesostructured Carbon CMK-1 by X-Ray Powder Diffraction and Electron Microscopy
The Journal of Physical Chemistry B. 2002. V.106. N47. P.12198-12202. DOI: 10.1021/jp0257653 WOS Scopus РИНЦ
Framework Characterization of Mesostructured Carbon CMK-1 by X-Ray Powder Diffraction and Electron Microscopy
The Journal of Physical Chemistry B. 2002. V.106. N47. P.12198-12202. DOI: 10.1021/jp0257653 WOS Scopus РИНЦ
Dates:
Submitted: | Mar 15, 2002 |
Published print: | Nov 1, 2002 |
Identifiers:
Web of science | WOS:000179543800018 |
Scopus | 2-s2.0-0037191890 |
Elibrary | 41810728 |
Chemical Abstracts | 2002:837567 |
Chemical Abstracts (print) | 138:43267 |
OpenAlex | W2052893920 |