Реферат: The effect of nickel oxide dispersity on the carbon formation capacity of high-percentage nickel catalysts for methane cracking was studied using 96% Ni-4% SiO2 as a model system. A new procedure for catalyst preparation was proposed. The procedure provides the nickel oxide dispersity independence of its concentration. It is based on the incorporation of silicon oxide in nickel oxide pores by the impregnation of the latter with an alcohol solution of hydrolyzed tetraethoxysilane. The necessary dispersity of NiO was achieved by its preliminary calcination at a certain temperature over a 300-900 °C range. Using the catalysts with different specific surface areas (from 200 to 0.7 m(2)/g, which correspond to the average sizes of NiO particles from 3 to >100 nm), we showed that their carbon capacity correlates with the specific surface area of nickel oxide and, hence, with the average size of NiO particles. The carbon capacity has a maximum (300 g C/g Ni) in the region of 50 m(2)/g (d(av) NiO similar to 19 nm). The results obtained point to the possibility of the formation of catalytic systems with the optimum size distribution of active particles.

Библиографическая ссылка: Ermakova M.A. , Ermakov D.Y. , Kuvshinov G.G. , Plyasova L.M.
Effect of Nickel Oxide Dispersity on Carbon Capacity of Nickel Catalysts for Low-Temperature Methane Cracking
Kinetics and Catalysis. 1998. V.39. N5. P.728-731. WOS Scopus РИНЦ CAPlusCA

Оригинальная: Ермакова М.А. , Ермаков Д.Ю. , Кувшинов Г.Г. , Плясова Л.М.
Влияние дисперсности оксида никеля на углеродоемкость никелевых катализаторов низкотемпературного разложения метана
Кинетика и катализ. 1998. Т.39. №5. С.791-794. РИНЦ

Даты:

Поступила в редакцию:

2 сент. 1997 г.

Идентификаторы БД:

Web of science:	WOS:000076734300028
Scopus:	2-s2.0-0342835006
РИНЦ:	13299247
Chemical Abstracts:	1998:740337
Chemical Abstracts (print):	130:40737

Цитирование в БД:

БД	Цитирований
Web of science	2
Scopus	2
РИНЦ	4