Liquid-Phase Hydrogenation of Thiophenes on Palladium Sulfide Catalysts | Sciact - CRIS-система Института катализа

Liquid-Phase Hydrogenation of Thiophenes on Palladium Sulfide Catalysts Научная публикация

Журнал

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Вых. Данные

Год: 2000, Том: 41, Номер: 3, Страницы: 388-393 Страниц : 6 DOI: 10.1007/BF02755377

Ключевые слова

Thiophene; Hydrogen Sulfide; Dodecane; Carbon Support; Benzothiophene

Авторы

Zirka A.A. ¹ , Mashkina A.V. ¹

Организации

1	Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, 630090, Novosibirsk, Russia

Palladium sulfide catalysts are active for the hydrogenation of thiophenes of different structure in hydrocarbons at 220-300 °С and 3.0-9.5 MPa. Thiophenes and benzothiophenes are close in reactivity. An increase in palladium sulfide concentration in the catalyst leads to an increase in the reaction rate per 1 g of the catalyst but has only a slight effect on the specific reaction rate of hydrogenation calculated per 1 g of Pd. The specific activity of palladium sulfide supported on aluminosilicate is one order of magnitude higher than that of PdS without a support and the catalysts supported on the aluminum oxide and carbon. The aluminosilicate-supported catalyst is also more selective.

Zirka A.A. , Mashkina A.V.
Liquid-Phase Hydrogenation of Thiophenes on Palladium Sulfide Catalysts
Kinetics and Catalysis. 2000. V.41. N3. P.388-393. DOI: 10.1007/BF02755377 WOS Scopus РИНЦ CAPlusCA OpenAlex

Зирка А.А. , Машкина А.В.
Жидкофазное гидрирование тиофенов в присутствии сульфидпалладиевых катализаторов
Кинетика и катализ. 2000. Т.41. №3. С.426-432. РИНЦ

Поступила в редакцию:	30 окт. 1998 г.
Опубликована в печати:	1 мая 2000 г.

Web of science:	WOS:000088248600015
Scopus:	2-s2.0-0034190111
РИНЦ:	13338454
Chemical Abstracts:	2000:521917
Chemical Abstracts (print):	133:119954
OpenAlex:	W2077850236

БД	Цитирований
Web of science	10
Scopus	9
РИНЦ	10
OpenAlex	9