Catalytic Steam Reforming of Methane: New Data on the Contribution of Homogeneous Radical Reactions in the Gas Phase: II. A Ruthenium Catalyst Full article
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Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2001, Volume: 42, Number: 6, Pages: 805-812 Pages count : 8 DOI: 10.1023/A:1013283216707 | ||
| Tags | Physical Chemistry; Nickel; Methane; Activation Energy; Steam | ||
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Abstract:
The kinetics of methane steam reforming and pyrolysis on Ru/Al2O3 (T= 650–750°C, P CH4 = 0.001–0.030 MPa) is studied. The values of the rates and activation energies are compared with the kinetic parameters for nickel catalysts. It was shown that steam reforming can occur on the ruthenium catalyst both heterogeneously and heterogeneously–homogeneously depending on the reaction conditions. Comparative activities of the Ru/Al2O3 and Ni–Al2O3catalysts are discussed under the conditions of purely heterogeneous and heterogeneous–homogeneous steam reforming.
Cite:
Bobrova I.I.
, Bobrov N.N.
, Chesnokov V.V.
, Parmon V.N.
Catalytic Steam Reforming of Methane: New Data on the Contribution of Homogeneous Radical Reactions in the Gas Phase: II. A Ruthenium Catalyst
Kinetics and Catalysis. 2001. V.42. N6. P.805-812. DOI: 10.1023/A:1013283216707 WOS Scopus РИНЦ ANCAN OpenAlex
Catalytic Steam Reforming of Methane: New Data on the Contribution of Homogeneous Radical Reactions in the Gas Phase: II. A Ruthenium Catalyst
Kinetics and Catalysis. 2001. V.42. N6. P.805-812. DOI: 10.1023/A:1013283216707 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Боброва И.И.
, Бобров Н.Н.
, Чесноков В.В.
, Пармон В.Н.
Конверсия метана водяным паром в присутствии катализаторов: новые данные о вкладе гомогенных радикальных реакций в газовой фазе. II. Рутениевый катализатор
Кинетика и катализ. 2001. Т.42. №6. С.882-889. РИНЦ
Конверсия метана водяным паром в присутствии катализаторов: новые данные о вкладе гомогенных радикальных реакций в газовой фазе. II. Рутениевый катализатор
Кинетика и катализ. 2001. Т.42. №6. С.882-889. РИНЦ
Dates:
| Submitted: | Jun 4, 2000 |
| Published print: | Nov 1, 2001 |
Identifiers:
| Web of science: | WOS:000173018500014 |
| Scopus: | 2-s2.0-0037494892 |
| Elibrary: | 13382984 |
| Chemical Abstracts: | 2002:30747 |
| Chemical Abstracts (print): | 136:249967 |
| OpenAlex: | W140792365 |