Kinetic Study of Catalytic Hydrogenation of Thiophene on a Palladium Sulfide Satalyst | Sciact - CRIS-system of Boreskov Institute of Catalysis

Kinetic Study of Catalytic Hydrogenation of Thiophene on a Palladium Sulfide Satalyst Full article

Journal

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Output data

Year: 2002, Volume: 43, Number: 4, Pages: 528-535 Pages count : 8 DOI: 10.1023/A:1019831203005

Tags

Hydrogen; Sulfide; Activation Energy; Catalysis; Palladium

Authors

Ermakova A. ¹ , Mashkina A.V. ¹ , Sakhaltueva L.G. ¹

Affiliations

1	Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk, 630090 Russia

The kinetics of thiophene hydrogenation on a palladium sulfide catalyst is studied at high hydrogen pressures. The reaction mainly occurs via the consecutive scheme: the reaction of thiophene with hydrogen results in the formation of tetrahydrothiophene, which partially decomposes under the action of hydrogen to yield butane and hydrogen sulfide. A kinetic model describing the reaction rates and the selectivity to tetrahydrothiophene at 0.2–3.0 MPa and 493–533 K is proposed. The rate constants and activation energies are determined. The effect of temperature and pressure on the maximal yield of tetrahydrothiophene is examined.

Ermakova A. , Mashkina A.V. , Sakhaltueva L.G.
Kinetic Study of Catalytic Hydrogenation of Thiophene on a Palladium Sulfide Satalyst
Kinetics and Catalysis. 2002. V.43. N4. P.528-535. DOI: 10.1023/A:1019831203005 WOS Scopus РИНЦ ANCAN OpenAlex

Ермакова А. , Машкина А.В. , Сахалтуева Л.Г.
Исследование кинетики каталитического гидрирования тиофена на сульфидпалладиевом катализаторе
Кинетика и катализ. 2002. Т.43. №4. С.572-579. РИНЦ

Submitted:	Jul 12, 2001
Published print:	Jul 1, 2002

Web of science:	WOS:000177849400012
Scopus:	2-s2.0-0038644394
Elibrary:	13396287
Chemical Abstracts:	2002:627509
Chemical Abstracts (print):	138:55574
OpenAlex:	W52444854

DB	Citing
Web of science	8
Scopus	9
Elibrary	9
OpenAlex	8