Effect of the Sulfate Sulfur Content and the Preparation Procedure on the Catalytic Properties of Sulfated Zirconium Oxide Full article
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Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2002, Volume: 43, Number: 4, Pages: 550-554 Pages count : 5 DOI: 10.1023/A:1019887320752 | ||
| Tags | Zirconium; Dehydration; Calcination; Sulfur Content; Catalytic Property | ||
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Abstract:
The effects of the composition and the procedure of preparing sulfated zirconium oxides on their catalytic properties in the reactions of 1-butene isomerization to 2-butenes and isobutanol dehydration were studied. The activity was found to depend on the nature of parent zirconium oxide, the sulfate sulfur content, and the temperature of calcination. Catalysts prepared from a crystalline oxide exhibited the highest activity. Their activity depends on the sulfate sulfur content. The calcination of catalysts at temperatures higher than 400°C resulted in a detectable loss of sulfate. The activity of sulfated oxides prepared from an amorphous oxide was noticeably lower; it depended only slightly on the temperature of calcination and sulfate sulfur content. The catalytic behavior of the sulfated oxide in both of the reactions is indicative of the absence of superstrong proton sites. Based on the results, assumptions on the nature of formed surface compounds were made.
Cite:
Shmachkova V.P.
, Kotsarenko N.S.
Effect of the Sulfate Sulfur Content and the Preparation Procedure on the Catalytic Properties of Sulfated Zirconium Oxide
Kinetics and Catalysis. 2002. V.43. N4. P.550-554. DOI: 10.1023/A:1019887320752 WOS Scopus РИНЦ ANCAN OpenAlex
Effect of the Sulfate Sulfur Content and the Preparation Procedure on the Catalytic Properties of Sulfated Zirconium Oxide
Kinetics and Catalysis. 2002. V.43. N4. P.550-554. DOI: 10.1023/A:1019887320752 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Шмачкова В.П.
, Коцаренко Н.С.
Влияние содержания сульфатной серы и способа приготовления на каталитические свойства сульфатированного оксида циркония
Кинетика и катализ. 2002. Т.43. №4. С.595-600. РИНЦ
Влияние содержания сульфатной серы и способа приготовления на каталитические свойства сульфатированного оксида циркония
Кинетика и катализ. 2002. Т.43. №4. С.595-600. РИНЦ
Dates:
| Submitted: | Aug 22, 2001 |
| Published print: | Jul 1, 2002 |
Identifiers:
| Web of science: | WOS:000177849400015 |
| Scopus: | 2-s2.0-0037562461 |
| Elibrary: | 13397858 |
| Chemical Abstracts: | 2002:627512 |
| Chemical Abstracts (print): | 137:371682 |
| OpenAlex: | W254860282 |