Intermediates of Asymmetric Oxidation Processes Catalyzed by Vanadium(V) Complexes Review
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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|---|---|---|---|
| Output data | Year: 2003, Volume: 44, Number: 3, Pages: 334-346 Pages count : 13 DOI: 10.1023/A:1024490817847 | ||
| Tags | Oxidation; Alcohol; Spectroscopy; Physical Chemistry; H2O2 | ||
| Authors |
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| Affiliations |
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Funding (3)
| 1 | Russian Foundation for Basic Research | 00-03-32438 |
| 2 | Russian Foundation for Basic Research | 01-03-06384 |
| 3 | Russian Foundation for Basic Research | 02-03-06185 |
Abstract:
The [VO(acac)2]/Schiff base [R-2-(N-3,5-di-tert-butylsalicylidene)amino-2-phenyl-1-ethanol, S-2-(N-3,5-di-tert-butylsalicylidene)amino-3,3-dimethyl-1-butanol, S-2-(N-3,5-di-tert-butylsalicylidene)amino-3-methyl-1-butanol, or R-2-(N-3,5-di-tert-butylsalicylidene)amino-3-phenyl-1-propanol]/H2O2 catalytic systems for the asymmetric oxidation of sulfides and the [VO(acac)2]/(3bR,4aR)-2-(3,4,4-trimethyl-3b,4,4a,5-tetrahydrocyclopropa[3,4]cyclopenta[1,2-c]pyrazol-1-yl)ethanol/tert-butyl hydroperoxide/ TBHP and VO(OAlkyl)3/[2,2]paracyclophane-4-carboxylic acid N-(1,1-dimethylethyl)-N-hydroxamide/TBHP catalytic systems for the asymmetric epoxidation of allylic alcohols were studied using 13C, 51V, and 17O NMR spectroscopy. The key intermediates of these systems (peroxo and alkylperoxo complexes of vanadium(V)) were detected, their structures in solution were studied, and the reactivity was evaluated.
Cite:
Bryliakov K.P.
, Talsi E.P.
Intermediates of Asymmetric Oxidation Processes Catalyzed by Vanadium(V) Complexes
Kinetics and Catalysis. 2003. V.44. N3. P.334-346. DOI: 10.1023/A:1024490817847 WOS Scopus РИНЦ ANCAN OpenAlex
Intermediates of Asymmetric Oxidation Processes Catalyzed by Vanadium(V) Complexes
Kinetics and Catalysis. 2003. V.44. N3. P.334-346. DOI: 10.1023/A:1024490817847 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Брыляков К.П.
, Талзи Е.П.
Интермедиаты процессов асимметрического окисления, катализируемых комплексами ванадия(V)
Кинетика и катализ. 2003. Т.44. №3. С.365-377. РИНЦ
Интермедиаты процессов асимметрического окисления, катализируемых комплексами ванадия(V)
Кинетика и катализ. 2003. Т.44. №3. С.365-377. РИНЦ
Dates:
| Submitted: | Oct 9, 2002 |
| Published print: | May 1, 2003 |
Identifiers:
| Web of science: | WOS:000183956000004 |
| Scopus: | 2-s2.0-0038153101 |
| Elibrary: | 13420951 |
| Chemical Abstracts: | 2003:480940 |
| Chemical Abstracts (print): | 139:276474 |
| OpenAlex: | W2950890980 |