New Y(La)–M–O Binary Systems (M = Ca, Sr, or Ba): Synthesis, Physicochemical Characterization, and Application As the Supports of Ruthenium Catalysts for Ammonia Synthesis Full article
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Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2004, Volume: 45, Number: 4, Pages: 541-546 Pages count : 6 DOI: 10.1023/B:KICA.0000038082.17355.61 | ||||
| Tags | Thermal Stability; Calcination; Binary System; Ruthenium; Y2O3 | ||||
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Abstract:
The effect of the nature of the alkaline-earth metal on the phase composition and specific surface area of new Y(La)-M-O binary oxide compositions (M = Ca, Sr, or Ba) prepared by coprecipitation was studied. These systems were found to contain mixed compounds (M2Y2O5, MY2O4, and MLa2O4), which are different in thermal stability, in addition to individual La2O3 or Y2O3 phases. The Y(La)-M-O compositions calcined at 450°C were characterized by a more developed specific surface area, as compared with that of individual La2O3 or Y2O3. An increase in the calcination temperature to 650°C was accompanied by a decrease in the specific surface area of binary compositions. Catalysts prepared by supporting K2[Ru4(CO)13] onto the Y(La)-M-O systems were active in ammonia synthesis at 250-400°C and atmospheric pressure. The most active of these catalysts, K2[Ru4(CO)13]/Y-Ba-O, provided a higher yield of NH3 at 250-300°C than analogous catalysts prepared with the use of well-known supports (Sibunit, CFC-1, and C/MgO).
Cite:
Ivanova A.S.
, Kalyuzhnaya E.S.
, Litvak G.S.
, Moroz E.M.
, Yunusov S.M.
, Lenenko V.S.
, Moroz B.L.
, Shur V.B.
, Likholobov V.A.
New Y(La)–M–O Binary Systems (M = Ca, Sr, or Ba): Synthesis, Physicochemical Characterization, and Application As the Supports of Ruthenium Catalysts for Ammonia Synthesis
Kinetics and Catalysis. 2004. V.45. N4. P.541-546. DOI: 10.1023/B:KICA.0000038082.17355.61 WOS Scopus РИНЦ ANCAN OpenAlex
New Y(La)–M–O Binary Systems (M = Ca, Sr, or Ba): Synthesis, Physicochemical Characterization, and Application As the Supports of Ruthenium Catalysts for Ammonia Synthesis
Kinetics and Catalysis. 2004. V.45. N4. P.541-546. DOI: 10.1023/B:KICA.0000038082.17355.61 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Иванова А.С.
, Калюжная Е.С.
, Литвак Г.С.
, Мороз Э.М.
, Юнусов С.М.
, Лененко В.С.
, Мороз Б.Л.
, Шур В.Б.
, Лихолобов В.А.
Новые бинарные системы Y(La)-M-O (M = Ca, Sr, Ba): синтез, физико-химические характеристики и применение в качестве носителей для рутениевых катализаторов синтеза аммиака
Кинетика и катализ. 2004. Т.45. №4. С.574-579. РИНЦ
Новые бинарные системы Y(La)-M-O (M = Ca, Sr, Ba): синтез, физико-химические характеристики и применение в качестве носителей для рутениевых катализаторов синтеза аммиака
Кинетика и катализ. 2004. Т.45. №4. С.574-579. РИНЦ
Dates:
| Submitted: | Jan 29, 2003 |
| Published print: | Jul 1, 2004 |
Identifiers:
| Web of science: | WOS:000223776200012 |
| Scopus: | 2-s2.0-4344661342 |
| Elibrary: | 13447058 |
| Chemical Abstracts: | 2004:671517 |
| Chemical Abstracts (print): | 142:323586 |
| OpenAlex: | W2090753383 |