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The Role of Hydrogen Bonds in the Pressure-Induced Structural Distortion of 4-Hydroxyacetanilide Crystals Научная публикация

Журнал Polish Journal of Chemistry
ISSN: 0137-5083
Вых. Данные Год: 2002, Том: 76, Номер: 9, Страницы: 1333-1346 Страниц : 14
Ключевые слова Acetaminophen, Diamond anvil cell, High pressure crystallography, High pressure IR-spectroscopy, Hydrogen bonds, P-hydroxyacetanilide, Paracetamol, Polymorphic transitions, Polymorphs
Авторы Boldyreva E.V. 1,4 , Shakhtshneider T.P. 1 , Ahsbahs H. 2 , Uchtmann H. 2 , Burgina E.B. 3 , Baltakhinov V.P. 3
Организации
1 Institute of Solid State Chemistry and Mechanochemistry, ul. Kutateladze 18, Novosibirsk 128, 630128, Russia
2 Philipps University of Marburg, Hans-Meerwein Strasse, 35032 Marburg/Lahn, Germany
3 Boreskov Institute of Catalysis, pr. Lavrent’eva 5, Novosibirsk 90, 630090, Russia
4 Novosibirsk State University

Реферат: Results of X-ray diffraction and IR-specroscopy studies of the role of hydrogen bonds in the structural distortion of the monoclinic and the orthorhombic polymorphs of paracetamol induced by hydrostatic pressure (up to 4-5 GPa) are analyzed. Two groups of phenomena were studied: (i) the anisotropic structural distortion of the same polymorph, (ii) transitions between the polymorphs induced by pressure. The bulk compressibilities of the two polymorphs are practically equal. The anisotropy of pressure-induced structural distortion is qualitatively different. Lattice expansion in particular crystallographic directions was observed for the monoclinic polymorph. With increasing pressure the intermolecular NH...O and OH...O hydrogen bonds contracted and the intramolecular angles between the planes of the phenyl ring and the acetamide group decreased. Pressure-induced transitions between the polymorphs were poorly reproducible and limited by nucleation of the new polymorph.
Библиографическая ссылка: Boldyreva E.V. , Shakhtshneider T.P. , Ahsbahs H. , Uchtmann H. , Burgina E.B. , Baltakhinov V.P.
The Role of Hydrogen Bonds in the Pressure-Induced Structural Distortion of 4-Hydroxyacetanilide Crystals
Polish Journal of Chemistry. 2002. V.76. N9. P.1333-1346. WOS Scopus РИНЦ CAPlusCA
Даты:
Поступила в редакцию: 29 нояб. 2001 г.
Опубликована в печати: 1 сент. 2002 г.
Идентификаторы БД:
Web of science: WOS:000177392200016
Scopus: 2-s2.0-0036712332
РИНЦ: 13400691
Chemical Abstracts: 2002:674627
Chemical Abstracts (print): 137:384473
Цитирование в БД:
БД Цитирований
Web of science 29
Scopus 29
РИНЦ 30