Microtacticity of Ethylene-Propylene Copolymers Prepared with Supported Catalysts of Different Composition ArticleGenre_short.SHORT_COMMUNICATION
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Polymer Science Series A
ISSN: 0965-545X , E-ISSN: 1555-6107 |
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| Output data | Year: 1996, Volume: 38, Number: 6, Pages: 609-613 Pages count : 5 | ||
| Tags | PROPENE | ||
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Abstract:
Microtacticity of propylene triads in ethylene-propylene copolymers prepared with supported titanium-magnesium catalysts of different stereospecificity, vanadium-magnesium catalysts of VCl4/MgCl2 + AlR3 type, and Zr(BH4)4/SiO2 and CrO3/SiO2 catalysts (both are active without organoaluminum cocatalysts) was studied by 13C NMR spectroscopy. Copolymers prepared with a titanium-magnesium catalyst containing stereoregulating additives show the highest microtacticity. Copolymers synthesized with catalysts of lower regiospecificity, especially with the chromium oxide catalyst, show minimal microtacticity of the propylene triads.
Cite:
Echevskaya L.G.
, Zakharov V.A.
Microtacticity of Ethylene-Propylene Copolymers Prepared with Supported Catalysts of Different Composition
Polymer Science Series A. 1996. V.38. N6. P.609-613. Scopus РИНЦ
Microtacticity of Ethylene-Propylene Copolymers Prepared with Supported Catalysts of Different Composition
Polymer Science Series A. 1996. V.38. N6. P.609-613. Scopus РИНЦ
Original:
Ечевская Л.Г.
, Захаров В.А.
Микротактичность сополимеров этилена с пропиленом, полученных на нанесенных катализаторах различного состава
Высокомолекулярные соединения. Серия А. 1996. Т.38. №6. С.959-963. WOS Scopus РИНЦ ANCAN
Микротактичность сополимеров этилена с пропиленом, полученных на нанесенных катализаторах различного состава
Высокомолекулярные соединения. Серия А. 1996. Т.38. №6. С.959-963. WOS Scopus РИНЦ ANCAN
Dates:
| Submitted: | Mar 23, 1995 |
| Published print: | Jun 1, 1996 |
Identifiers:
| Scopus: | 2-s2.0-0030305843 |
| Elibrary: | 13233799 |