Selective Water Sorbents for Multiple Applications, 5. LiBr Confined in Mesopores of Silica Gel: Sorption Properties Full article
| Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
||||
|---|---|---|---|---|---|
| Output data | Year: 1998, Volume: 63, Number: 1, Pages: 81-88 Pages count : 8 DOI: 10.1007/BF02475434 | ||||
| Tags | Lithium bromide, Silica gel, Sorption, Vapor | ||||
| Authors |
|
||||
| Affiliations |
|
Abstract:
This paper presents sorption properties of a selective water sorbent based on mesoporous KSKG silica gel as a host matrix and lithium bromide as a hygroscopic salt. Sorption isobars, isochores and isotherms measured at T=40–120°C and partial vapor pressures of 7.5–81.0 mbar indicated two types of water sorption: 1) formation of a solid crystalline LiBr monohydrate at low amounts of sorbed water, and 2) vapor absorption by the salt solution at higher sorptions. Sorption properties of the LiBr monohydrate are found to change significantly due to salt impregnation into the mesoporous silica gel, whereas the solution confinement to the mesopores did not change its water sorption properties as compared to the bulk solution. Desorption curves follow a first order kinetics in the temperature range of 60–130°C at different vapor pressures.
Cite:
Gordeeva L.G.
, Restuccia G.
, Cacciola G.
, Aristov Y.I.
Selective Water Sorbents for Multiple Applications, 5. LiBr Confined in Mesopores of Silica Gel: Sorption Properties
Reaction Kinetics and Catalysis Letters. 1998. V.63. N1. P.81-88. DOI: 10.1007/BF02475434 WOS Scopus РИНЦ ANCAN OpenAlex
Selective Water Sorbents for Multiple Applications, 5. LiBr Confined in Mesopores of Silica Gel: Sorption Properties
Reaction Kinetics and Catalysis Letters. 1998. V.63. N1. P.81-88. DOI: 10.1007/BF02475434 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Dec 10, 1996 |
| Accepted: | Apr 2, 1997 |
| Published print: | Jan 1, 1998 |
Identifiers:
| Web of science: | WOS:000072459800013 |
| Scopus: | 2-s2.0-0002596377 |
| Elibrary: | 13281472 |
| Chemical Abstracts: | 1998:192887 |
| Chemical Abstracts (print): | 129:8987 |
| OpenAlex: | W2034510111 |