On the Nature of Factors Determining Reactivity of Strongly Bound Surface Species as Intermediates in Heterogeneous Catalytic Redox Reactions | Sciact - CRIS-система Института катализа

On the Nature of Factors Determining Reactivity of Strongly Bound Surface Species as Intermediates in Heterogeneous Catalytic Redox Reactions Научная публикация

Журнал

Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837

Вых. Данные

Год: 1999, Том: 66, Номер: 2, Страницы: 337-341 Страниц : 5 DOI: 10.1007/BF02475810

Ключевые слова

Klaus reaction, Mechanism of catalytic redox reactions, Methanol synthesis, Selective reduction of nitrogen oxides by hydrocarbons, Strongly bound intermediates

Авторы

Sadykov V.A. ¹ , Rozovskii A.Ya. ² , Lunin V.V. ³ , Lin G.I. ² , Alikina G.M. ¹ , Buchtiyarova G.A. ¹ , Zolotovskii B.P. ¹ , Beloshapkin S.A. ⁴

Организации

1	Boreskov Institute of Catalysis, Novosibirsk 630090, Russia
2	Topchlev Institute of Petrochemical Synthesis RAS, Moscow, Russia
3	Chemical Department, Lomonosov Moscow State University, Moscow, Russia
4	Department of Natural Sciences, Novisibirsk State University, Novosibirsk, Russia

Информация о финансировании (2)

1	Российский фонд фундаментальных исследований	95-03-09622
2	Российский фонд фундаментальных исследований	95-03-09675

The rate-limiting stage of heterogeneous catalytic redox reactions with participation of strongly bound surface species, such as nitrates, carbonates and sulfites, is the interaction of these heteroatomic oxidants with the reducing agents. It appears to be mainly determined by their bonding strength with the surface, being independent of the nature of the central atom (carbon, sulfur, nitrogen) and the energy of its bond with oxygen.

Sadykov V.A. , Rozovskii A.Y. , Lunin V.V. , Lin G.I. , Alikina G.M. , Buchtiyarova G.A. , Zolotovskii B.P. , Beloshapkin S.A.
On the Nature of Factors Determining Reactivity of Strongly Bound Surface Species as Intermediates in Heterogeneous Catalytic Redox Reactions
Reaction Kinetics and Catalysis Letters. 1999. V.66. N2. P.337-341. DOI: 10.1007/BF02475810 WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	13 июл. 1998 г.
Принята к публикации:	11 янв. 1999 г.
Опубликована в печати:	1 мар. 1999 г.

Web of science:	WOS:000079504700021
Scopus:	2-s2.0-0037528746
РИНЦ:	13307172
Chemical Abstracts:	1999:613472
Chemical Abstracts (print):	131:205242
OpenAlex:	W1999122596

БД	Цитирований
Web of science	8
Scopus	4
РИНЦ	5
OpenAlex	8