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On Metal Blocking in Micropores of Carbon Supports Full article

Journal Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837
Output data Year: 2000, Volume: 71, Number: 1, Pages: 165-171 Pages count : 7 DOI: 10.1023/A:1010367123342
Tags Activated carbon supports, Metal blocking, Platinum, Pore-size effect
Authors Okhlopkova L.B. 1 , Lisitsyn A.S. 1 , Boehm H.P. 2 , Likholobov V.A. 1
Affiliations
1 Boreskov Institute of Catalysis, Novosibirsk, 630090 Russia
2 Institut fur Anorganische Chemie der Universitat Munchen, Munchen, Germany

Abstract: Platinum catalysts prepared on activated carbon supports of different origin are compared in the hydrogenation of cyclohexene and cyclooctene, which differ much in their reactivity. A decrease in the catalytic activity upon decreasing the dimensions of the micropores in the support and the size of the supported metal particles has been confirmed. The results give evidence against a trivial role of the diffusional factor in such an effect and indicate complete blocking of part of the metal surface in narrow pores.
Cite: Okhlopkova L.B. , Lisitsyn A.S. , Boehm H.P. , Likholobov V.A.
On Metal Blocking in Micropores of Carbon Supports
Reaction Kinetics and Catalysis Letters. 2000. V.71. N1. P.165-171. DOI: 10.1023/A:1010367123342 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Aug 14, 2000
Accepted: Aug 25, 2000
Published print: Sep 1, 2000
Identifiers:
Web of science: WOS:000166028500023
Scopus: 2-s2.0-0347013843
Elibrary: 13341105
Chemical Abstracts: 2001:3282
Chemical Abstracts (print): 134:178207
OpenAlex: W31560732
Citing:
DB Citing
Web of science 10
Scopus 10
Elibrary 13
OpenAlex 10
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