EPR Detection and Characterization of High-Valent Manganese Complexes in MnIII(Salen) Catalyzed Aerobic Olefin Epoxidation Full article
| Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
||
|---|---|---|---|
| Output data | Year: 2000, Volume: 71, Number: 1, Pages: 183-191 Pages count : 9 DOI: 10.1023/A:1010323308321 | ||
| Tags | Aerobic enantioselective epoxidation, EPR, Intermediates, Mn(Salen) complexes | ||
| Authors |
|
||
| Affiliations |
|
Funding (1)
| 1 | Russian Foundation for Basic Research | 99-03-32448 |
Abstract:
Using EPR, high-valent MnIV complexes have been detected in Mukaiyama's catalytic system, MnIII(Salen)/Isobutyraldehyde/O2, and shown to form also in the model system MnIII(Salen)/Peroxyisobutyric acid. Their possible role in alkene epoxidation is discussed.
Cite:
Bryliakov K.P.
, Khavrutskii I.V.
, Talsi E.P.
, Kholdeeva O.A.
EPR Detection and Characterization of High-Valent Manganese Complexes in MnIII(Salen) Catalyzed Aerobic Olefin Epoxidation
Reaction Kinetics and Catalysis Letters. 2000. V.71. N1. P.183-191. DOI: 10.1023/A:1010323308321 WOS Scopus РИНЦ ANCAN OpenAlex
EPR Detection and Characterization of High-Valent Manganese Complexes in MnIII(Salen) Catalyzed Aerobic Olefin Epoxidation
Reaction Kinetics and Catalysis Letters. 2000. V.71. N1. P.183-191. DOI: 10.1023/A:1010323308321 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Aug 14, 2000 |
| Accepted: | Aug 25, 2000 |
| Published print: | Sep 1, 2000 |
Identifiers:
| Web of science: | WOS:000166028500026 |
| Scopus: | 2-s2.0-0034262940 |
| Elibrary: | 13338593 |
| Chemical Abstracts: | 2001:3285 |
| Chemical Abstracts (print): | 134:178240 |
| OpenAlex: | W292856407 |