Acidic Properties of Sulfated Zirconia Full article
| Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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| Output data | Year: 2000, Volume: 71, Number: 2, Pages: 385-391 Pages count : 7 DOI: 10.1023/A:1010304032536 | ||
| Tags | Acid sites, FTIR, Sulfated zirconia | ||
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Abstract:
IR spectroscopy of adsorbed probe molecules (CO, pyridine) is used to characterize the acidic properties of sulfated zirconia derived from zirconium oxide and hydroxide. Their acidic properties are found to be similar. The strength of the Lewis and Brönsted site measured by the frequency shift of adsorbed CO is lower than that in zeolites. It is concluded that sulfated zirconia have no superacid Brönsted and Lewis sites. Brönsted sites capable of protonating pyridine vanish when calcining the catalysts at temperature above 773 K, but the strength and concentration of the Lewis acid sites (LAS) do not change.
Cite:
Paukshtis E.A.
, Shmachkova V.P.
, Kotsarenko N.S.
Acidic Properties of Sulfated Zirconia
Reaction Kinetics and Catalysis Letters. 2000. V.71. N2. P.385-391. DOI: 10.1023/A:1010304032536 WOS Scopus РИНЦ ANCAN OpenAlex
Acidic Properties of Sulfated Zirconia
Reaction Kinetics and Catalysis Letters. 2000. V.71. N2. P.385-391. DOI: 10.1023/A:1010304032536 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Published print: | Nov 1, 2000 |
| Submitted: | Nov 8, 2000 |
Identifiers:
| Web of science: | WOS:000167137100026 |
| Scopus: | 2-s2.0-0034319035 |
| Elibrary: | 13356425 |
| Chemical Abstracts: | 2001:159948 |
| Chemical Abstracts (print): | 134:198655 |
| OpenAlex: | W2158543822 |