Adsorption of Hydrogen on Reduced Copper Chromite Научная публикация
Журнал |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Вых. Данные | Год: 2003, Том: 79, Номер: 1, Страницы: 85-92 Страниц : 8 DOI: 10.1023/A:1024159717910 | ||
Ключевые слова | Copper chromite, Hydrogen adsorption | ||
Авторы |
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Организации |
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Реферат:
Temperature programmed desorption and volumetric methods in static conditions were used to study hydrogen adsorption on the surface of metallic copper particles produced by the partial reduction of copper chromite CuCr2O4 with hydrogen. In the temperature range 300-573 K and in the range of medium surface coverages by hydrogen, the main state of adsorbed hydrogen reveals the heat of adsorption q= 78 kJ/mol and activation energy of adsorption Ea = 69 kJ/mol. In the temperature range 77-300 K, an adsorption state with lower heat and activation energy was found, indicating a non-uniformity of the copper surface within ca. 8% of the total number of surface sites.
Библиографическая ссылка:
Simentsova I.I.
, Davydova L.P.
, Khasin A.V.
, Yurieva T.M.
Adsorption of Hydrogen on Reduced Copper Chromite
Reaction Kinetics and Catalysis Letters. 2003. V.79. N1. P.85-92. DOI: 10.1023/A:1024159717910 WOS Scopus РИНЦ CAPlusCA OpenAlex
Adsorption of Hydrogen on Reduced Copper Chromite
Reaction Kinetics and Catalysis Letters. 2003. V.79. N1. P.85-92. DOI: 10.1023/A:1024159717910 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: | 22 нояб. 2002 г. |
Принята к публикации: | 29 нояб. 2002 г. |
Опубликована в печати: | 1 мая 2003 г. |
Идентификаторы БД:
Web of science: | WOS:000183538700011 |
Scopus: | 2-s2.0-0037499874 |
РИНЦ: | 13439888 |
Chemical Abstracts: | 2003:451643 |
Chemical Abstracts (print): | 139:169795 |
OpenAlex: | W36049756 |