Kinetics of the Medium-Temperature Reduction of Copper Chromite with Hydrogen Научная публикация
| Журнал |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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| Вых. Данные | Год: 2004, Том: 82, Номер: 2, Страницы: 355-361 Страниц : 7 DOI: 10.1023/B:REAC.0000034848.70151.05 | ||
| Ключевые слова | Copper chromite, Hydrogen, Reaction kinetics | ||
| Авторы |
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| Организации |
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Реферат:
The static volumetric method was used to study the kinetics of copper chromite CuCr2O4 reduction with hydrogen at 50-80 kPa and 498, 523 and 580 K. The rate of copper chromite reduction is maximal initially and decreases monotonically with time. This observation suggests that the reduction is not a topochemical process. The apparent activation energy of the reaction equals initially 107 kJ/mole. The results obtained argue for a particular mechanism of the copper chromite reduction via redox substitution of hydrogen for copper in the chromite and, therefore, agree with earlier data obtained by various structural and adsorption methods. Specific features of the reduction mechanism are discussed.
Библиографическая ссылка:
Simentsova I.I.
, Khasin A.V.
, Davydova L.P.
, Yurieva T.M.
Kinetics of the Medium-Temperature Reduction of Copper Chromite with Hydrogen
Reaction Kinetics and Catalysis Letters. 2004. V.82. N2. P.355-361. DOI: 10.1023/B:REAC.0000034848.70151.05 WOS Scopus РИНЦ CAPlusCA OpenAlex
Kinetics of the Medium-Temperature Reduction of Copper Chromite with Hydrogen
Reaction Kinetics and Catalysis Letters. 2004. V.82. N2. P.355-361. DOI: 10.1023/B:REAC.0000034848.70151.05 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 8 мар. 2004 г. |
| Принята к публикации: | 12 мар. 2004 г. |
| Опубликована в печати: | 1 июл. 2004 г. |
Идентификаторы БД:
| Web of science: | WOS:000223217500020 |
| Scopus: | 2-s2.0-3142685520 |
| РИНЦ: | 13464345 |
| Chemical Abstracts: | 2004:565951 |
| Chemical Abstracts (print): | 141:162855 |
| OpenAlex: | W2084588442 |