Reactions of Nitrosoarenes Containing Electron-Withdrawing Substituents with Coordinated CO. Synthesis and Structure of Complexes Pd2(OAc) 2(p-ClC6H4N[p-ClC6H 3NO])2 and Pd2(OAc)2(o-ClC 6H4N[o-ClC6H3NO])2 Full article
| Journal |
Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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| Output data | Year: 2004, Volume: 53, Number: 4, Pages: 819-824 Pages count : 6 DOI: 10.1023/B:RUCB.0000037849.06365.7f | ||||
| Tags | arylnitrenes, carbonyl complexes, chloronitrosobenzene, clusters, nitrosoarenes, palladium | ||||
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| Affiliations |
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Funding (2)
| 1 | Russian Foundation for Basic Research | 04-03-32436 |
| 2 | The Ministry of Education and Science of the Russian Federation | Е02 5.0 185 |
Abstract:
The reaction of tetranuclear Pd4(μ-COOCH3)4(μ-CO)4 cluster (1a) with p- and o-chloronitrosobenzenes was found to give dinuclear nitrosoamide complexes, Pd2(OAc)2(p-ClC6H4N[p-ClC6H3NO])2 (4) and Pd2(OAc)2(o-ClC6H4N[o-ClC6H3NO])2 (5), respectively. The formation of complexes 4 and 5 is accompanied by evolution of CO2, resulting from oxidation of CO coordinated in cluster 1. Complexes 4 and 5 were characterized by elemental analysis and IR and 1H NMR spectroscopy; their structures were studied by EXAFS. The reactions of dinuclear complex 4 with molecular hydrogen and CO were studied. The major products of reduction of 4 with hydrogen include metallic palladium, acetic acid, cyclohexanone, and molecular nitrogen. Treatment of complex 4 with CO under mild conditions (1 atm, 20 °C) affords p-chlorophenyl isocyanate.
Cite:
Orlova S.T.
, Stromnova T.A.
, Kazyulʹkin D.N.
, Boganova L.I.
, Kochubey D.I.
, Novgorodov B.N.
Reactions of Nitrosoarenes Containing Electron-Withdrawing Substituents with Coordinated CO. Synthesis and Structure of Complexes Pd2(OAc) 2(p-ClC6H4N[p-ClC6H 3NO])2 and Pd2(OAc)2(o-ClC 6H4N[o-ClC6H3NO])2
Russian Chemical Bulletin. 2004. V.53. N4. P.819-824. DOI: 10.1023/B:RUCB.0000037849.06365.7f WOS Scopus РИНЦ ANCAN OpenAlex
Reactions of Nitrosoarenes Containing Electron-Withdrawing Substituents with Coordinated CO. Synthesis and Structure of Complexes Pd2(OAc) 2(p-ClC6H4N[p-ClC6H 3NO])2 and Pd2(OAc)2(o-ClC 6H4N[o-ClC6H3NO])2
Russian Chemical Bulletin. 2004. V.53. N4. P.819-824. DOI: 10.1023/B:RUCB.0000037849.06365.7f WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Орлова С.Т.
, Стромнова Т.А.
, Казюлькин Д.Н.
, Боганова Л.И.
, Кочубей Д.И.
, Новгородов Б.Н.
Взаимодействие нитрозоаренов, содержащих электроноакцепторные заместители, с координированным CO: синтез и строение комплексов Pd2(OAc)2(p-ClC6H4N[p-ClC6H3NO])2 и Pd2(OAc)2(o-ClC6H4N[o-ClC6H3NO])2
Известия Академии наук. Серия химическая. 2004. №4. С.783-788. РИНЦ
Взаимодействие нитрозоаренов, содержащих электроноакцепторные заместители, с координированным CO: синтез и строение комплексов Pd2(OAc)2(p-ClC6H4N[p-ClC6H3NO])2 и Pd2(OAc)2(o-ClC6H4N[o-ClC6H3NO])2
Известия Академии наук. Серия химическая. 2004. №4. С.783-788. РИНЦ
Dates:
| Submitted: | Oct 2, 2003 |
| Accepted: | Dec 8, 2003 |
| Published print: | Apr 1, 2004 |
Identifiers:
| Web of science: | WOS:000223667400016 |
| Scopus: | 2-s2.0-4444276439 |
| Elibrary: | 13447225 |
| Chemical Abstracts: | 2004:669571 |
| Chemical Abstracts (print): | 142:105916 |
| OpenAlex: | W2319694359 |