Platinum Electrodeposits on Glassy Carbon: The Formation Mechanism, Morphology, and Adsorption Properties Full article
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Russian Journal of Electrochemistry
ISSN: 1023-1935 , E-ISSN: 1608-3342 |
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| Output data | Year: 2000, Volume: 36, Number: 7, Pages: 741-751 Pages count : 11 DOI: 10.1007/BF02757674 | ||||
| Tags | Glassy Carbon; Scanning Tunneling Microscopy; Scanning Tunneling Microscopy Image; Reversible Hydrogen Electrode; Transmission Electron Microscopy Data | ||||
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Abstract:
The deposition of platinum on glassy carbon (GC) is studied by chronoamperometry. Basic tendencies of the formation of aggregate platinum particles on the oxidized carbon surface are established. These include a primary instantaneous nucleation of platinum under diffusion control and the beginning of a secondary nucleation prior to filling primary active centers. The deposit morphology is examined by ex situ methods of scanning electron microscopy (SEM), transmission electron microscopy (TEM), and scanning tunneling microscopy (STM). A globular structure of platinum, formed by crystallites 3–5 nm in size, is revealed. A comparison of the STM, SEM, and TEM data demonstrates a high information value and accuracy of STM in studies of disperse materials in both nanometer and submicron ranges. Various coulometry techniques intended for the determination of the true surface area of deposited platinum are compared. The most informative techniques are the voltammetry of desorption of copper adatoms and chemisorbed carbon monoxide at, respectively, low and high platinum contents. Differences in the formation kinetics and properties of aggregate particles in Pt/GC and Pt/Pt are found, specifically, smaller Pt/GC crystallites and higher degrees of their concrescence (screening).
Cite:
Sherstyuk O.V.
, Pronkin S.N.
, Chuvilin A.L.
, Salanov A.N.
, Savinova E.R.
, Tsirlina G.A.
, Petrii O.A.
Platinum Electrodeposits on Glassy Carbon: The Formation Mechanism, Morphology, and Adsorption Properties
Russian Journal of Electrochemistry. 2000. V.36. N7. P.741-751. DOI: 10.1007/BF02757674 WOS Scopus РИНЦ ANCAN OpenAlex
Platinum Electrodeposits on Glassy Carbon: The Formation Mechanism, Morphology, and Adsorption Properties
Russian Journal of Electrochemistry. 2000. V.36. N7. P.741-751. DOI: 10.1007/BF02757674 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Шерстюк О.В.
, Пронькин C.Н.
, Чувилин А.Л.
, Саланов А.Н.
, Савинова Е.Р.
, Цирлина Г.А.
, Петрий О.А.
Электролитические осадки платины на стеклоуглероде-закономерности формирования, морфология и адсорбционные свойства
Электрохимия. 2000. Т.36. №7. С.836-847. РИНЦ
Электролитические осадки платины на стеклоуглероде-закономерности формирования, морфология и адсорбционные свойства
Электрохимия. 2000. Т.36. №7. С.836-847. РИНЦ
Dates:
| Submitted: | Jul 5, 1999 |
| Published print: | Jul 1, 2000 |
Identifiers:
| Web of science: | WOS:000088469600009 |
| Scopus: | 2-s2.0-0033798699 |
| Elibrary: | 13348639 |
| Chemical Abstracts: | 2000:578675 |
| Chemical Abstracts (print): | 133:273274 |
| OpenAlex: | W2042025190 |