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129Xe NMR Study of Xe Adsorption on Multiwall Carbon Nanotubes Научная публикация

Журнал Solid State Nuclear Magnetic Resonance
ISSN: 0926-2040 , E-ISSN: 1527-3326
Вых. Данные Год: 2005, Том: 28, Номер: 2-4, Страницы: 135-141 Страниц : 7 DOI: 10.1016/j.ssnmr.2005.07.004
Ключевые слова 129Xe NMR, Carbon nanotubes, Porosity
Авторы Romanenko K.V. 1,2 , Fonseca A. 3 , Dumonteil S. 3 , Nagy J.B. 3 , d’Espinose de Lacaillerie J. 2 , Lapina O.B. 1 , Fraissard J. 2
Организации
1 Boreskov Institute of Catalysis, Siberian Branch of Russian Academy of Sciences, 630090 Novosibirsk, Russia
2 Laboratoire de Physique Quantique, UMR CNRS 7142, Ecole Supe´rieure de Physique et de Chimie Industrielles (ESPCI), 75231 Paris Cedex 05, France
3 Laboratoire de Resonance Magnetique Nucleaire, FUNDP, 61 Rue de Bruxelles, B-5000 Namur, Belgium

Информация о финансировании (1)

1 Российский фонд фундаментальных исследований 04-03-33070

Реферат: 129Xe NMR spectroscopy has been used to study the adsorption of Xe on multi-wall carbon nanotubes (MWCNT). The results obtained have shown the 129Xe NMR ability to probe the intercrystalline (aggregate) and the inner porosity of CNT. In particular, the effects on porosity of tubes openings by hydrogen exposure and of ball milling were examined. Dramatic changes observed in the 129Xe NMR spectra after moderate ball milling of MWCNTs were attributed to the destruction of the initial intercrystalline pore structure and to the Xe access inside the nanotubes. To examine the exchange dynamics the mixture of as-made and milled MWCNTs was studied with one- and two-dimensional (1D and 2D) 129Xe NMR. The exchange between the interior of milled nanotubes and the aggregate pores of as-made MWCNTs was fast on the NMR acquisition time scale. The Xenon exchange between the interior of the as-made MWCNTs and the large aggregate pores occurred on a longer time scale of 10 ms, as was established by 2D 129Xe NMR exchange spectroscopy. Variable temperature 129Xe NMR data were also discussed and analyzed in terms of the fast exchange approximation.
Библиографическая ссылка: Romanenko K.V. , Fonseca A. , Dumonteil S. , Nagy J.B. , d’Espinose de Lacaillerie J. , Lapina O.B. , Fraissard J.
129Xe NMR Study of Xe Adsorption on Multiwall Carbon Nanotubes
Solid State Nuclear Magnetic Resonance. 2005. V.28. N2-4. P.135-141. DOI: 10.1016/j.ssnmr.2005.07.004 WOS Scopus РИНЦ CAPlusCA PMID OpenAlex
Даты:
Поступила в редакцию: 30 мая 2005 г.
Опубликована online: 18 авг. 2005 г.
Опубликована в печати: 1 сент. 2005 г.
Идентификаторы БД:
Web of science: WOS:000234325100009
Scopus: 2-s2.0-29144519724
РИНЦ: 13488175
Chemical Abstracts: 2005:1320899
Chemical Abstracts (print): 145:15399
PMID (PubMed): 16102946
OpenAlex: W2024005665
Цитирование в БД:
БД Цитирований
Web of science 32
Scopus 33
РИНЦ 33
OpenAlex 30
Альметрики: