Investigation of Heterogeneous Catalytic Reactions by the in situ 1H NMR Microimaging | Sciact - CRIS-system of Boreskov Institute of Catalysis

Investigation of Heterogeneous Catalytic Reactions by the in situ 1H NMR Microimaging Full article

Conference

Catalysis for sustainable development : Russian-Dutch Workshop
22-26 Jun 2002 , Novosibirsk, Russia

Journal

Химия в интересах устойчивого развития
ISSN: 0869-8538

Output data

Year: 2003, Volume: 11, Number: 1, Pages: 109-116 Pages count : 8

Authors

Koptyug I.V. ¹ , Kulikov A.V. ² , Lysova A.A. ^1,2,3 , Kirillov V.A. ² , Parmon V.N. ² , Sagdeev R.Z. ¹

Affiliations

1	International Tomography Center, Siberian Branch of the Russian Academy of Sciences, Ul. Institutskaya 3A, Novosibirsk 630090 (Russia)
2	G. K. Boreskov Institute of Catalysis, Siberan Branch of the Russian Academy of Sciences, Pr. Akademika Lavrentyeva 5, Novosibirsk 630090 (Russia)
3	Novosibirsk State University, Ul. Pirogova 2, Novosibirsk 630090 (Russia)

Funding (5)

1	Russian Foundation for Basic Research	02-03-32770
2	Russian Foundation for Basic Research	00-15-97450
3	Russian Foundation for Basic Research	00-15-97446
4	Zamaraev International Charitable Scientific Foundation
5	Siberian Branch of the Russian Academy of Sciences	36

The NMR microimaging is used for the first time as an in situ method to study two model three-phase heterogeneous catalytic reactions with strong exothermicity. It is shown for the α-methylstyrene hydrogenation that in the course of the reaction, two domains coexist inside the catalyst grain which differ in the liquid phase content. The 2D maps of the liquid distribution in the course of this reaction are obtained. The reaction of the hydrogen peroxide decomposition at moderate activity of the catalyst and the H2O2 concentrations in the range of (0.03-3) M is shown to occur only in a thin layer near the catalyst surface. The influence of the medium inhomogeneity on the behaviour of the Belousov - Zhabotinsky chemical oscillator reaction is investigated as well.

Koptyug I.V. , Kulikov A.V. , Lysova A.A. , Kirillov V.A. , Parmon V.N. , Sagdeev R.Z.
Investigation of Heterogeneous Catalytic Reactions by the in situ 1H NMR Microimaging
Химия в интересах устойчивого развития. 2003. V.11. N1. P.109-116. РИНЦ ANCAN

Koptyug I.V. , Kulikov A.V. , Lysova A.A. , Kirillov V.A. , Parmon V.N. , Sagdeev R.Z.
Investigation of Heterogeneous Catalytic Reactions by the in situ 1H NMR MicroImaging
Chemistry for Sustainable Development. 2003. V.11. N1. P.109-116. РИНЦ

Elibrary:	17749415
Chemical Abstracts:	2003:278798
Chemical Abstracts (print):	139:117074

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