Oxidative Hydroxylation Using Dinitrogen Monoxide: A Possible Route for Organic Synthesis over Zeolites | Sciact - CRIS-система Института катализа

Oxidative Hydroxylation Using Dinitrogen Monoxide: A Possible Route for Organic Synthesis over Zeolites Обзор

Журнал

Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875

Вых. Данные

Год: 1993, Том: 98, Номер: 1, Страницы: 1-20 Страниц : 20 DOI: 10.1016/0926-860X(93)85021-G, 10.1002/chin.199334102

Ключевые слова

dinitrogen monoxide, oxidative hydroxylation, phenol synthesis, selective oxidation, zeolites, ZSM-5

Авторы

Panov G.I. ¹ , Kharitonov A.S. ¹ , Sobolev V.I. ¹

Организации

1	Boreskov Institute of Catalysis, Novosibirsk 630090 (Russian Federation)

The use of zeolites as catalysts for selective oxidation reactions has been considered. Particular attention has been paid to recent studies of a gas-phase oxidative hydroxylation of aromatics by dinitrogen monoxide. The best results were obtained for a simple reaction, the oxidation of benzene to phenol over Fe-containing ZSM-5 zeolites. It proceeds with nearly 100% selectivity at 25–30% benzene conversion. Further progress in this promising direction, the hydroxylation of aromatics, can provide new efficient technologies in organic synthesis. Peculiarities of dinitrogen monoxide as an oxidant and the reaction mechanism are discussed.

Panov G.I. , Kharitonov A.S. , Sobolev V.I.
Oxidative Hydroxylation Using Dinitrogen Monoxide: A Possible Route for Organic Synthesis over Zeolites
Applied Catalysis A: General. 1993. V.98. N1. P.1-20. DOI: 10.1016/0926-860X(93)85021-G, 10.1002/chin.199334102 WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	25 мая 1992 г.
Опубликована в печати:	6 мая 1993 г.
Опубликована online:	18 сент. 2001 г.

Web of science:	WOS:A1993LB21900001
Scopus:	2-s2.0-0027910422
РИНЦ:	31080875
Chemical Abstracts:	1993:256920
Chemical Abstracts (print):	118:256920
OpenAlex:	W2039635823

БД	Цитирований
Web of science	192
Scopus	214
РИНЦ	213
OpenAlex	190