Ferrisilicate Analogs of ZSM-5 Zeolite as Catalysts for One-Step Oxidation of Benzene to Phenol Научная публикация
| Журнал |
Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875 |
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| Вых. Данные | Год: 1993, Том: 98, Номер: 1, Страницы: 33-43 Страниц : 11 DOI: 10.1016/0926-860X(93)85023-I | ||
| Ключевые слова | acidity, benzene to phenol oxidation, FeZSM-5 zeolite, iron, mechanisms, nitrous oxide as oxidant, phenol, zeolites | ||
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| Организации |
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Реферат:
The role of iron in the catalytic properties of ZSM-5 ferrisilicate analogs in the oxidation of benzene to phenol by dinitrogen monoxide has been studied within a wide range of iron concentrations (from 0.003 to 4.8 wt.-% Fe2O3). The samples of the Fe-Si system with optimal iron content, as well as previously studied Fe-Al-Si samples of the same zeolite structure, were found to be far superior to known catalysts. A reaction mechanism is suggested, where the active form of the surface oxygen produced by dinitrogen monoxide decomposition is of key importance. Zeolite acidity was tested and its role in the catalytic activity is discussed.
Библиографическая ссылка:
Kharitonov A.S.
, Sheveleva G.A.
, Panov G.I.
, Sobolev V.I.
, Paukshtis Y.A.
, Romannikov V.N.
Ferrisilicate Analogs of ZSM-5 Zeolite as Catalysts for One-Step Oxidation of Benzene to Phenol
Applied Catalysis A: General. 1993. V.98. N1. P.33-43. DOI: 10.1016/0926-860X(93)85023-I WOS Scopus РИНЦ OpenAlex CAPlusCA
Ferrisilicate Analogs of ZSM-5 Zeolite as Catalysts for One-Step Oxidation of Benzene to Phenol
Applied Catalysis A: General. 1993. V.98. N1. P.33-43. DOI: 10.1016/0926-860X(93)85023-I WOS Scopus РИНЦ OpenAlex CAPlusCA
Даты:
| Поступила в редакцию: | 15 авг. 1992 г. |
| Принята к публикации: | 15 янв. 1993 г. |
| Опубликована в печати: | 6 мая 1993 г. |
| Опубликована online: | 18 сент. 2001 г. |
Идентификаторы БД:
| ≡ Web of science: | WOS:A1993LB21900003 |
| ≡ Scopus: | 2-s2.0-0027910426 |
| ≡ РИНЦ: | 31099072 |
| ≡ OpenAlex: | W1969502482 |
| ≡ Chemical Abstracts: | 1993:256953 |
| ≡ Chemical Abstracts (print): | 118:256953 |