Alkylation of Naphthalene with Methanol over SAPO-11 Molecular Sieve Synthesized by Different Crystallization Methods | Sciact - CRIS-system of Boreskov Institute of Catalysis

Alkylation of Naphthalene with Methanol over SAPO-11 Molecular Sieve Synthesized by Different Crystallization Methods Full article

Journal

Microporous and Mesoporous Materials
ISSN: 1387-1811 , E-ISSN: 1873-3093

Output data

Year: 2013, Volume: 181, Pages: 132-140 Pages count : 9 DOI: 10.1016/j.micromeso.2013.06.034

Tags

2,6-Dimethylnaphthalene, IR spectroscopy, Microwave irradiation, Naphthalene alkylation, SAPO-11

Authors

Min Liu ¹ , Wei Wu ¹ , Kikhtyanin O.V. ^2,3 , Linfei Xiao ¹ , Toktarev A.V. ² , Gaoliang Wang ¹ , Aijuan Zhao ¹ , Smirnova M.Yu. ² , Echevsky G.V. ²

Affiliations

1	Key Laboratory of Chemical Engineering Process & Technology for High-Efficiency Conversion, College of Heilongjiang Province, International Joint Research Centre for Catalytic Technology, School of Chemistry and Material Sciences, Heilongjiang University,
2	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk 630090, Russia
3	Research Institute of Inorganic Chemistry, RENTECH-UniCRE, Chempark Litvínov, Záluzˇí, Litvínov 436 70, Czech Republic

Funding (3)

1	National Natural Science Foundation of China	21076065
2	National Natural Science Foundation of China	21211120164
3	Ministry of Science and Technology of the People's Republic of China	2013DFR40570

Silicoaluminophosphate SAPO-11 molecular sieves were synthesized by both traditional hydrothermal and microwave irradiation methods. Their properties were characterized by multiple physico-chemical methods and compared in the alkylation of naphthalene with methanol. The results obtained indicate that the different preparation methods result in differences in the characteristics of the prepared samples. Compared to SAPO-11 obtained by the traditional hydrothermal method, samples synthesized by microwave irradiation possessed a lower content of silica, larger dimensions of both the individual crystals and polycrystalline agglomerates, and a lower amount of strong Brönsted and Lewis acid sites. Investigation of the properties of the prepared SAPO-11 materials in a naphthalene methylation reaction revealed that all of the samples demonstrated good activity in the reaction and catalytic stability with Time-On-Stream regardless of the synthesis method used. A higher 2,6-dimethylnaphthalene/2,7-dimethylnaphthalene molar ratio was observed for SAPO-11 samples prepared by microwave irradiation, which was attributed to a milder acidity of these materials.

Min L. , Wei W. , Kikhtyanin O.V. , Linfei X. , Toktarev A.V. , Gaoliang W. , Aijuan Z. , Smirnova M.Y. , Echevsky G.V.
Alkylation of Naphthalene with Methanol over SAPO-11 Molecular Sieve Synthesized by Different Crystallization Methods
Microporous and Mesoporous Materials. 2013. V.181. P.132-140. DOI: 10.1016/j.micromeso.2013.06.034 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Mar 1, 2013
Accepted:	Jun 21, 2013
Published online:	Jul 1, 2013
Published print:	Nov 15, 2013

Web of science:	WOS:000325676500019
Scopus:	2-s2.0-84882268139
Elibrary:	20457992
Chemical Abstracts:	2013:1495652
Chemical Abstracts (print):	159:518047
OpenAlex:	W2013811413

DB	Citing
Web of science	25
Scopus	26
Elibrary	27
OpenAlex	27