Abstract: The low-temperature oxidation of CO to CO2 by solutions of PdSO4 and various heteropolyacids (HPAs) has been studied. The dependence of the reaction rate on the potential of HPA determined by its composition has been obtained. At moderate values of HPA potentials. lg W depends linearly on E. Carbonyl complexes of reduced palladium show the highest catalytic activity. The activity of the SiO2-supported homogeneous component has also been examined. The kinetic dependences indicate similar mechanisms for the reaction occurring in solution or on the surface of an inert support. During the oxidation of CO by dioxygen, only those HPAs are catalytically active whose reduced forms are oxidized by O2.

Cite: Zhizhina E.G. , Kuznetsova L.I. , Maksimovskaya R.I. , Pavlova S.N. , Matveev K.I.
Oxidation of CO to CO2 by Heteropolyacids in the Presence of Palladium
Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic). 1986. V.38. N3. P.345-353. DOI: 10.1016/0304-5102(86)85044-1 WOS Scopus РИНЦ ANCAN OpenAlex

Dates:

Submitted:	Jun 28, 1985
Accepted:	Apr 30, 1986
Published print:	Dec 1, 1986
Published online:	Oct 2, 2001

Identifiers:

Web of science:	WOS:A1986F261300016
Scopus:	2-s2.0-0022881004
Elibrary:	31009321
Chemical Abstracts:	1987:73626
Chemical Abstracts (print):	106:73626
OpenAlex:	W2048696110

Citing:

DB	Citing
Web of science	37
Scopus	34
Elibrary	33
OpenAlex	34

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