Study of the Mechanism of Ethylene Oxidation by Palladium(II) Complexes Containing Nitro and/or Nitrato Ligands in Chloroform Научная публикация
| Журнал |
Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic)
ISSN: 0304-5102 |
||
|---|---|---|---|
| Вых. Данные | Год: 1989, Том: 50, Номер: 2, Страницы: 167-179 Страниц : 13 DOI: 10.1016/0304-5102(89)85060-6 | ||
| Ключевые слова | ethylene oxidation palladium nitrogen oxide; nitropalladium ethylene oxidation mechanism; nitratopalladium ethylene oxidation mechanism; propylene oxidation palladium nitrogen oxide | ||
| Авторы |
|
||
| Организации |
|
Реферат:
Complexes of Pd(NOn)2−mClmL2 (where n = 2, 3; m = 0,1, 2; L= CH3CN, CD3CN) were synthesized and their reactivities towards ethylene and propylene oxidation in a chloroform medium were investigated. The detailed mechanism of ethylene oxidation by dinitro- and mono-nitrato complexes of palladium in chloroform solutions was studied by IR and 1H NMR spectroscopy. The structures and routes of decomposition of the intermediates to reaction end products are proposed.
Библиографическая ссылка:
Beck I.E.
, Gusevskaya E.V.
, Stepanov A.G.
, Likholobov V.A.
, Nekipelov V.M.
, Yermakov Y.I.
, Zamaraev K.I.
Study of the Mechanism of Ethylene Oxidation by Palladium(II) Complexes Containing Nitro and/or Nitrato Ligands in Chloroform
Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic). 1989. V.50. N2. P.167-179. DOI: 10.1016/0304-5102(89)85060-6 WOS Scopus РИНЦ CAPlusCA OpenAlex
Study of the Mechanism of Ethylene Oxidation by Palladium(II) Complexes Containing Nitro and/or Nitrato Ligands in Chloroform
Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic). 1989. V.50. N2. P.167-179. DOI: 10.1016/0304-5102(89)85060-6 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 7 апр. 1988 г. |
| Принята к публикации: | 26 июл. 1988 г. |
| Опубликована в печати: | 16 мар. 1989 г. |
| Опубликована online: | 2 окт. 2001 г. |
Идентификаторы БД:
| Web of science: | WOS:A1989T397100007 |
| Scopus: | 2-s2.0-0024621830 |
| РИНЦ: | 31088132 |
| Chemical Abstracts: | 1989:496447 |
| Chemical Abstracts (print): | 111:96447 |
| OpenAlex: | W1996449233 |