Study of the Effect of Pr and Ho Ions on Pd/SiO2 Properties Using Catalysts Prepared via Supported Organometallic Complexes Научная публикация
| Конференция |
VI International Symposium on Relation between Homogeneous and Heterogeneous Catalysis 25-29 сент. 1989 , Pisa |
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| Журнал |
Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic)
ISSN: 0304-5102 |
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| Вых. Данные | Год: 1989, Том: 55, Номер: 1, Страницы: 84-93 Страниц : 10 DOI: 10.1016/0304-5102(89)80244-5 | ||
| Ключевые слова | Carbon Monoxide--Absorption; Methanol--Synthesis; Organometallics; Spectroscopy, Infrared--Applications | ||
| Авторы |
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| Организации |
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Реферат:
FT-IR and XPS methods have been used to study the formation, the state of the components and the forms of CO adsorption on (Pd + Pr)/SiO2 catalysts prepared from organometallic precursors. The catalysts contain finely dispersed particles of metallic Pd coordinated with Pr3+ ions. A correlation between the Eb value for the Pd 3d level of modified Pd and its turnover number (TON) activity in CH3OH synthesis has been demonstrated. The high activity of promoted Pd seems to be due to activation of CO molecules on mixed active sites consisting of Pd atoms and lanthanide ions.
Библиографическая ссылка:
Nogin Y.N.
, Paukshtis E.A.
, Pashis A.V.
, Ryndin Y.A.
Study of the Effect of Pr and Ho Ions on Pd/SiO2 Properties Using Catalysts Prepared via Supported Organometallic Complexes
Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic). 1989. V.55. N1. P.84-93. DOI: 10.1016/0304-5102(89)80244-5 WOS Scopus РИНЦ CAPlusCA OpenAlex
Study of the Effect of Pr and Ho Ions on Pd/SiO2 Properties Using Catalysts Prepared via Supported Organometallic Complexes
Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic). 1989. V.55. N1. P.84-93. DOI: 10.1016/0304-5102(89)80244-5 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Опубликована в печати: | 1 нояб. 1989 г. |
| Опубликована online: | 2 окт. 2001 г. |
Идентификаторы БД:
| Web of science: | WOS:A1989CG95900008 |
| Scopus: | 2-s2.0-0024768603 |
| РИНЦ: | 31093300 |
| Chemical Abstracts: | 1990:101833 |
| Chemical Abstracts (print): | 112:101833 |
| OpenAlex: | W1989314726 |