1,4-Bis(1,2,6-triphenyl-4-pyridyl)benzene as a Novel Hydrophobic Electron Relay for Dihydrogen Evolution in Photocatalytic Systems Based on Lipid Vesicles Научная публикация
| Журнал |
Journal of Photochemistry and Photobiology A: Chemistry
ISSN: 1010-6030 , E-ISSN: 1873-2666 |
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| Вых. Данные | Год: 1994, Том: 83, Номер: 2, Страницы: 153-159 Страниц : 7 DOI: 10.1016/1010-6030(94)03812-0 | ||
| Ключевые слова | DITHIONITE; REDUCTION; VIOLOGENS; KINETICS; OXYGEN | ||
| Авторы |
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| Организации |
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Реферат:
1,4-Bis(1,2,6-triphenyl-4-pyridyl)benzene (“benzoviologen”) is an efficient lipophilic reversible electron relay, which can be used to build structurally organized molecular systems based on lipid vesicles for photocatalytic water cleavage. Benzoviologen has an advantage over the widely used conventional lipophilic viologens, since its reduced forms possess more negative reduction potentials. This promotes photostimulated transmembrane electron transfer and catalytic water reduction at neutral or even slightly basic pH. The kinetic properties of benzoviologen and its capacity to produce one- and two-electron-reduced forms were studied. The ability to couple vectorial transmembrane electron phototransfer with dihydrogen evolution from water over a dispersed Pd catalyst was proven experimentally.
Библиографическая ссылка:
Efimova E.V.
, Lymar S.V.
, Parmon V.N.
1,4-Bis(1,2,6-triphenyl-4-pyridyl)benzene as a Novel Hydrophobic Electron Relay for Dihydrogen Evolution in Photocatalytic Systems Based on Lipid Vesicles
Journal of Photochemistry and Photobiology A: Chemistry. 1994. V.83. N2. P.153-159. DOI: 10.1016/1010-6030(94)03812-0 WOS Scopus РИНЦ CAPlusCA OpenAlex
1,4-Bis(1,2,6-triphenyl-4-pyridyl)benzene as a Novel Hydrophobic Electron Relay for Dihydrogen Evolution in Photocatalytic Systems Based on Lipid Vesicles
Journal of Photochemistry and Photobiology A: Chemistry. 1994. V.83. N2. P.153-159. DOI: 10.1016/1010-6030(94)03812-0 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 15 июн. 1993 г. |
| Принята к публикации: | 8 февр. 1994 г. |
| Опубликована в печати: | 4 окт. 1994 г. |
| Опубликована online: | 7 нояб. 2001 г. |
Идентификаторы БД:
| Web of science: | WOS:A1994PL00900009 |
| Scopus: | 2-s2.0-0346924556 |
| РИНЦ: | 31112149 |
| Chemical Abstracts: | 1995:79847 |
| Chemical Abstracts (print): | 122:326150 |
| OpenAlex: | W1967536264 |