Radical Intermediates in the Photoinduced Formation of Benzene Cation Radicals over H-ZSM-5 Zeolites Научная публикация
| Журнал |
Journal of Physical Chemistry (up to 1996)
ISSN: 0022-3654 |
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| Вых. Данные | Год: 1994, Том: 98, Номер: 31, Страницы: 7551-7554 Страниц : 4 DOI: 10.1021/j100082a027 | ||
| Ключевые слова | ZSM-5 ZEOLITES; IN SITU; ADSORPTION; EPR | ||
| Авторы |
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| Организации |
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Реферат:
Radical particles are shown to appear under irradiation (hv ≥ 2.8 eV) of H-ZSM-S zeolites with adsorbed benzene. The particles appeared to be benzene cation-radical precursors over the zeolite. Heating resulted in irreversible destruction of the particles and emergence of a benzene cation-radical spectrum. The obtained radicals have no detectable hyperfine splittings on the protons, their spectrum remaining almost the same when deuterobenzene was used. The possible structure of the particles is discussed.
Библиографическая ссылка:
Bolshov V.A.
, Volodin A.M.
, Zhidomirov G.M.
, Shubin A.A.
, Bedilo A.F.
Radical Intermediates in the Photoinduced Formation of Benzene Cation Radicals over H-ZSM-5 Zeolites
Journal of Physical Chemistry (up to 1996). 1994. V.98. N31. P.7551-7554. DOI: 10.1021/j100082a027 WOS Scopus РИНЦ CAPlusCA OpenAlex
Radical Intermediates in the Photoinduced Formation of Benzene Cation Radicals over H-ZSM-5 Zeolites
Journal of Physical Chemistry (up to 1996). 1994. V.98. N31. P.7551-7554. DOI: 10.1021/j100082a027 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 29 нояб. 1993 г. |
| Принята к публикации: | 10 мая 1994 г. |
| Опубликована в печати: | 1 авг. 1994 г. |
| Опубликована online: | 1 мая 2002 г. |
Идентификаторы БД:
| Web of science: | WOS:A1994PA68900027 |
| Scopus: | 2-s2.0-0001153241 |
| РИНЦ: | 22618784 |
| Chemical Abstracts: | 1994:495704 |
| Chemical Abstracts (print): | 121:95704 |
| OpenAlex: | W2000811204 |