New Cobalt Catalysts for the Synthesis of Diethyl Ketone from Ethylene, Carbon-Monoxide, and Water | Sciact - CRIS-система Института катализа

New Cobalt Catalysts for the Synthesis of Diethyl Ketone from Ethylene, Carbon-Monoxide, and Water Письма в редакцию

Журнал

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Вых. Данные

Год: 1984, Том: 25, Номер: 2, Страницы: 424-425 Страниц : 2

Авторы

Startseva L.Y. ¹ , Semikolenov V.A. ¹ , Lisitsyn A.S. ¹ , Likholobov V.A. ¹ , Ermakov Y.I. ¹

Организации

1	Institute of Catalysis, Siberian Branch U.S.S.R. Academy of Sciences

In testing the possibility of employing the catalysts used to carry out a hydrocarboxylation process, the authors found that the catalyst prepared by rapid pyrolysis of Co2(CO)8 adsorbed on the surface of a carbon support converted a C2H4:CO:H2O gas mixture into diethyl ketone at an appreciable rate even at 423 degree K. When catalysts obtained by rapid pyrolysis of Co2(CO)8 adsorbed on oxide supports were used, the predominant process was hydrogenation of ethylene to ethane. In a number of cases, traces of propionic aldehyde, ethyl propionate, and diethyl ketone were found in the reaction products. The unusual catalytic properties of the Co/carbon-support sample are explained by the particular state of the deposited metal.

Startseva L.Y. , Semikolenov V.A. , Lisitsyn A.S. , Likholobov V.A. , Ermakov Y.I.
New Cobalt Catalysts for the Synthesis of Diethyl Ketone from Ethylene, Carbon-Monoxide, and Water
Kinetics and Catalysis. 1984. V.25. N2. P.424-425. WOS Scopus РИНЦ

Старцева Л.Я. , Семиколенов В.А. , Лисицын А.С. , Лихолобов В.А. , Ермаков Ю.И.
Новые кобальтовые катализаторы синтеза диэтилкетона из этилена, окиси углерода и воды
Кинетика и катализ. 1984. Т.25. №2. С.506. РИНЦ CAPlusCA

Поступила в редакцию:	23 сент. 1983 г.
Опубликована в печати:	1 мар. 1984 г.

Web of science:	WOS:A1984TS58800026
Scopus:	2-s2.0-0021390717
РИНЦ:	30602980

БД	Цитирований
Web of science	1
Scopus	1
РИНЦ	1