Influence of the Nature of the Oxidizing-Agents on the Mechanism of the Oxidation of Carbon-Monoxide in the Presence of an Aqua Complex of Palladium(II) | Sciact - CRIS-система Института катализа

Influence of the Nature of the Oxidizing-Agents on the Mechanism of the Oxidation of Carbon-Monoxide in the Presence of an Aqua Complex of Palladium(II) Научная публикация

Журнал

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Вых. Данные

Год: 1985, Том: 26, Номер: 2, Страницы: 404-408 Страниц : 5

Авторы

Zhizhina E.G. ¹ , Matveev K.I. ¹ , Kuznetsova L.I. ¹

Организации

1	Institute of Catalysis, Siberian Branch U.S.S.R. Academy of Sciences

The kinetics of CO oxidation was studied in the presence of aquo complexes of Pd(II), VO2+, Fe3+, and heteropoly-acids H3PMO12O40, H4PMo11VO40, and H4PW11VO40. A comparison of the present and published results on oxidation with strong oxidizing agents, such as Cr2O72-, of Ce4+, reveals that for a fast oxidation, the oxidation potential should be 0.7-1.0 V. The intermediate carbonyl complexes of partially reduced Pd are the most active catalysts of the oxidation.

Zhizhina E.G. , Matveev K.I. , Kuznetsova L.I.
Influence of the Nature of the Oxidizing-Agents on the Mechanism of the Oxidation of Carbon-Monoxide in the Presence of an Aqua Complex of Palladium(II)
Kinetics and Catalysis. 1985. V.26. N2. P.404-408. WOS РИНЦ

Жижина Е.Г. , Матвеев К.И. , Кузнецова Л.И.
Влияние природы окислителей на механизм процесса окисления оксида углерода в присутствии аквакомплекса палладия (II)
Кинетика и катализ. 1985. Т.26. №2. С.461-465. РИНЦ CAPlusCA

Поступила в редакцию:	13 окт. 1983 г.
Опубликована в печати:	1 мар. 1985 г.

Web of science:	WOS:A1985AUZ1800017
РИНЦ:	30603111

БД	Цитирований
Web of science	3