Investigation of the Influence of the Acid Properties of Zeolites on the Catalytic Activity in the Isomerization of n-butane to Isobutane | Sciact - CRIS-system of Boreskov Institute of Catalysis

Investigation of the Influence of the Acid Properties of Zeolites on the Catalytic Activity in the Isomerization of n-butane to Isobutane Full article

Journal

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Output data

Year: 1985, Volume: 26, Number: 6, Pages: 1205-1209 Pages count : 5

Authors

Soltanov R.I. ¹ , Paukshtis E.A. ¹ , Yurchenko E.N. ¹ , Dadashev B.A. ¹ , Poladov F.M. ¹ , Kasumov F.B. ¹

Affiliations

1	Institute of Catalysis, Siberian Branch U.S.S.R. Academy of Sciences

The isomerization of n-butane to isobutane at 673 degree K was studied on metal-zeolite catalysts Pd0/Me2 plus NaY and Pd0/Me2 plus CaNaY, where Me2 plus equals Ni2 plus , Co2 plus , Mn2 plus , and Ca2+ . It was shown that the rate of polymerization depends on the strength and concentration of the aprotic sites, formed by isolated Me2 plus and Ca2 plus cations. An equation was obtained for the dependence of the specific activity on the strength of the sites, characterized by the heats of adsorption of carbon monoxide (Q//C//O).

Soltanov R.I. , Paukshtis E.A. , Yurchenko E.N. , Dadashev B.A. , Poladov F.M. , Kasumov F.B.
Investigation of the Influence of the Acid Properties of Zeolites on the Catalytic Activity in the Isomerization of n-butane to Isobutane
Kinetics and Catalysis. 1985. V.26. N6. P.1205-1209. WOS Scopus РИНЦ

Солтанов Р.И. , Паукштис Е.А. , Юрченко Э.Н. , Дадашев Б.А. , Поладов Ф.М. , Касумов Ф.Б.
Исследование влияния кислотных свойств цеолитов на каталитическую активность в реакции изомеризации н-бутана в изобутан
Кинетика и катализ. 1985. Т.26. №6. С.1398-1403. РИНЦ ANCAN

Submitted:	Apr 19, 1984
Published print:	Nov 1, 1985

Web of science:	WOS:A1985C968100020
Scopus:	2-s2.0-0022156181
Elibrary:	30603148

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