IR Spectroscopic Study of the Mechanism of Deep Oxidation of 2-Propanol on Cupric Oxide under Catalytic Reaction conditions | Sciact - CRIS-system of Boreskov Institute of Catalysis

IR Spectroscopic Study of the Mechanism of Deep Oxidation of 2-Propanol on Cupric Oxide under Catalytic Reaction conditions Full article

Journal

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Output data

Year: 1992, Volume: 33, Number: 1, Pages: 107-113 Pages count : 7

Tags

ADSORPTION; ACETONE; MgO; NiO

Authors

Dobrynkin N.M. ¹ , Davydov A.A. ¹ , Budneva A.A. ¹ , Popovskii V.V. ¹ , Rogov V.A. ¹ , Serebryakov V.F. ¹

Affiliations

1	Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR

The spectrokinetic method was used to study surface compounds and the kinetics of their conversion, to establish the structure of intermediate surface forms and the sequence of their conversions, and to determine kinetic parameters of the individual steps. It was shown that under the conditions of a catalytic reaction a successive chain of conversions of surface structures is realized: isopropylate ---- --> adsorbed acetone structures --- --> carboxylate + formate ---- --> carbon dioxide, with the step of oxidation of carboxylate structures being the limiting step.

Dobrynkin N.M. , Davydov A.A. , Budneva A.A. , Popovskii V.V. , Rogov V.A. , Serebryakov V.F.
IR Spectroscopic Study of the Mechanism of Deep Oxidation of 2-Propanol on Cupric Oxide under Catalytic Reaction conditions
Kinetics and Catalysis. 1992. V.33. N1. P.107-113. WOS РИНЦ

Добрынкин Н.М. , Давыдов А.А. , Буднева А.А. , Поповский В.В. , Рогов В.А. , Серебряков В.Ф.
ИК-спектроскопическое исследование механизма глубокого окисления пропанола-2 на оксиде меди в условиях осуществления каталитической реакции
Кинетика и катализ. 1992. Т.33. №1. С.133-141. РИНЦ ANCAN

Submitted:	Jan 2, 1990
Published print:	Jan 1, 1992

Web of science:	WOS:A1992JP32300001
Elibrary:	30598186

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