Abstract: The effect of the conditions of activation of magnesium chloride on the substructure and composition of applied titanium-magnesium catalysts of polymerization of ethylene was studied; the catalysts were prepared by different methods: 1) by adsorption of TiCl4 on highly disperse magnesium chloride prepared from unsolvated butylmagnesium chloride; 2) by adsorption of TiCl4 on magnesium chloride activated by grinding; 3) by combined grinding of magnesium chloride with titanium tetrachloride. It was shown that TiCl4 reacts with defects in the structure of the magnesium chloride, whose concentration is correlated with the size of the regions of coherent scattering determined from x-ray data.

Cite: Zakharov V.A. , Perkovets D.V. , Bukatov G.D. , Sergeev S.A. , Moroz E.M. , Makhtarulin S.I.
Effect of the Conditions of Activation of Magnesium Chloride on the Substructure and Composition of Applied Titanium-Magnesium Catalysts of Polymerization of Ethylene
Kinetics and Catalysis. 1989. V.29. N4, part 2. P.774-779. WOS Scopus РИНЦ

Original: Захаров В.А. , Перковец Д.В. , Букатов Г.Д. , Сергеев С.А. , Мороз Э.М. , Махтарулин С.И.
Влияние условий активации хлорида магния на субструктуру и состав нанесенных титанмагниевых катализаторов полимеризации этилена
Кинетика и катализ. 1988. Т.29. №4. С.903-908. РИНЦ ANCAN

Dates:

Submitted:	Dec 10, 1986
Published print:	Jul 1, 1989

Identifiers:

Web of science:	WOS:A1988U344200002
Scopus:	2-s2.0-0024613301
Elibrary:	31127624

Citing:

DB	Citing
Web of science	1
Scopus	1